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1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone
In the title compound, C(13)H(15)ClN(2)O, there are two crystallographically independent but conformationally similar (E)-molecules in the asymmetric unit [dihedral angles between the phenyl ring and a common planar fragment of the 1,3-diazepane moiety = 47.34 (16) and 48.00 (16)°]. The seven-membe...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685108/ https://www.ncbi.nlm.nih.gov/pubmed/23795127 http://dx.doi.org/10.1107/S1600536813013858 |
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author | Zhang, Xiao-Wei Xia, Jian-Hui Xu, Zhao-Hui Wang, Li-Ben Yu, Chu-Yi |
author_facet | Zhang, Xiao-Wei Xia, Jian-Hui Xu, Zhao-Hui Wang, Li-Ben Yu, Chu-Yi |
author_sort | Zhang, Xiao-Wei |
collection | PubMed |
description | In the title compound, C(13)H(15)ClN(2)O, there are two crystallographically independent but conformationally similar (E)-molecules in the asymmetric unit [dihedral angles between the phenyl ring and a common planar fragment of the 1,3-diazepane moiety = 47.34 (16) and 48.00 (16)°]. The seven-membered ring system adopts a chair conformation in both molecules. In the crystal, N—H⋯O hydrogen bonds lead to chains extending along the b-axis direction. |
format | Online Article Text |
id | pubmed-3685108 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36851082013-06-21 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone Zhang, Xiao-Wei Xia, Jian-Hui Xu, Zhao-Hui Wang, Li-Ben Yu, Chu-Yi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(15)ClN(2)O, there are two crystallographically independent but conformationally similar (E)-molecules in the asymmetric unit [dihedral angles between the phenyl ring and a common planar fragment of the 1,3-diazepane moiety = 47.34 (16) and 48.00 (16)°]. The seven-membered ring system adopts a chair conformation in both molecules. In the crystal, N—H⋯O hydrogen bonds lead to chains extending along the b-axis direction. International Union of Crystallography 2013-05-25 /pmc/articles/PMC3685108/ /pubmed/23795127 http://dx.doi.org/10.1107/S1600536813013858 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Xiao-Wei Xia, Jian-Hui Xu, Zhao-Hui Wang, Li-Ben Yu, Chu-Yi 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
title | 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
title_full | 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
title_fullStr | 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
title_full_unstemmed | 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
title_short | 1-(4-Chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
title_sort | 1-(4-chlorophenyl)-2-(1,3-diazepan-2-ylidene)ethanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685108/ https://www.ncbi.nlm.nih.gov/pubmed/23795127 http://dx.doi.org/10.1107/S1600536813013858 |
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