1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate

In the main mol­ecule of the title compound, C(21)H(18)Br(3)N(3)·CH(2)Cl(2), the triazinane ring adopts a chair conformation with three 4-brom­ophenyl substituents, two in diaxial positions and the third in an equatorial arrangement (eaa). The torsion angles around the N—C bonds in the triazinane ri...

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Detalles Bibliográficos
Autores principales: Chebbah, Mahmoud, Bouchemma, Ahcene, Bouacida, Sofiane, Lefrada, Leila, Bouhenguel, Mustapha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685111/
https://www.ncbi.nlm.nih.gov/pubmed/23795130
http://dx.doi.org/10.1107/S1600536813013743
Descripción
Sumario:In the main mol­ecule of the title compound, C(21)H(18)Br(3)N(3)·CH(2)Cl(2), the triazinane ring adopts a chair conformation with three 4-brom­ophenyl substituents, two in diaxial positions and the third in an equatorial arrangement (eaa). The torsion angles around the N—C bonds in the triazinane ring are in the range 55.6 (5)–60.1 (5)°. The structure can be described as being built up of alternating layers along the b axis with the CH(2)Cl(2) solvent mol­ecules sandwiched between these layers. No classical hydrogen-bonding inter­actions are observed in the crystal structure.

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