1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate

In the main mol­ecule of the title compound, C(21)H(18)Br(3)N(3)·CH(2)Cl(2), the triazinane ring adopts a chair conformation with three 4-brom­ophenyl substituents, two in diaxial positions and the third in an equatorial arrangement (eaa). The torsion angles around the N—C bonds in the triazinane ri...

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Autores principales: Chebbah, Mahmoud, Bouchemma, Ahcene, Bouacida, Sofiane, Lefrada, Leila, Bouhenguel, Mustapha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685111/
https://www.ncbi.nlm.nih.gov/pubmed/23795130
http://dx.doi.org/10.1107/S1600536813013743
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author Chebbah, Mahmoud
Bouchemma, Ahcene
Bouacida, Sofiane
Lefrada, Leila
Bouhenguel, Mustapha
author_facet Chebbah, Mahmoud
Bouchemma, Ahcene
Bouacida, Sofiane
Lefrada, Leila
Bouhenguel, Mustapha
author_sort Chebbah, Mahmoud
collection PubMed
description In the main mol­ecule of the title compound, C(21)H(18)Br(3)N(3)·CH(2)Cl(2), the triazinane ring adopts a chair conformation with three 4-brom­ophenyl substituents, two in diaxial positions and the third in an equatorial arrangement (eaa). The torsion angles around the N—C bonds in the triazinane ring are in the range 55.6 (5)–60.1 (5)°. The structure can be described as being built up of alternating layers along the b axis with the CH(2)Cl(2) solvent mol­ecules sandwiched between these layers. No classical hydrogen-bonding inter­actions are observed in the crystal structure.
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spelling pubmed-36851112013-06-21 1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate Chebbah, Mahmoud Bouchemma, Ahcene Bouacida, Sofiane Lefrada, Leila Bouhenguel, Mustapha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the main mol­ecule of the title compound, C(21)H(18)Br(3)N(3)·CH(2)Cl(2), the triazinane ring adopts a chair conformation with three 4-brom­ophenyl substituents, two in diaxial positions and the third in an equatorial arrangement (eaa). The torsion angles around the N—C bonds in the triazinane ring are in the range 55.6 (5)–60.1 (5)°. The structure can be described as being built up of alternating layers along the b axis with the CH(2)Cl(2) solvent mol­ecules sandwiched between these layers. No classical hydrogen-bonding inter­actions are observed in the crystal structure. International Union of Crystallography 2013-05-25 /pmc/articles/PMC3685111/ /pubmed/23795130 http://dx.doi.org/10.1107/S1600536813013743 Text en © Chebbah et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chebbah, Mahmoud
Bouchemma, Ahcene
Bouacida, Sofiane
Lefrada, Leila
Bouhenguel, Mustapha
1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
title 1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
title_full 1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
title_fullStr 1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
title_full_unstemmed 1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
title_short 1,3,5-Tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
title_sort 1,3,5-tris(4-bromo­phen­yl)-1,3,5-triazin­ane di­chloro­methane monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685111/
https://www.ncbi.nlm.nih.gov/pubmed/23795130
http://dx.doi.org/10.1107/S1600536813013743
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