5-Benz­yloxy-3-methyl-1-tosyl-1H-indole

The title compound, C(23)H(21)NO(3)S, represents one of the few examples of a 5-substituted indole with a toluene­sulfonyl group bonded to the N atom. The benzyl group adopts a synclinal geometry with respect to the indole ring [dihedral angle = 59.95 (4)°], while the tolyl ring is oriented close to...

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Detalles Bibliográficos
Autores principales: Pozza Silveira, Gustavo, Oliver, Allen G., Noll, Bruce C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685113/
https://www.ncbi.nlm.nih.gov/pubmed/23795132
http://dx.doi.org/10.1107/S1600536813014001
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author Pozza Silveira, Gustavo
Oliver, Allen G.
Noll, Bruce C.
author_facet Pozza Silveira, Gustavo
Oliver, Allen G.
Noll, Bruce C.
author_sort Pozza Silveira, Gustavo
collection PubMed
description The title compound, C(23)H(21)NO(3)S, represents one of the few examples of a 5-substituted indole with a toluene­sulfonyl group bonded to the N atom. The benzyl group adopts a synclinal geometry with respect to the indole ring [dihedral angle = 59.95 (4)°], while the tolyl ring is oriented close to perpendicular to the indole ring, making a dihedral angle of 81.85 (3)°. The indole N atom exhibits a slight pyramidalization.
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spelling pubmed-36851132013-06-21 5-Benz­yloxy-3-methyl-1-tosyl-1H-indole Pozza Silveira, Gustavo Oliver, Allen G. Noll, Bruce C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(21)NO(3)S, represents one of the few examples of a 5-substituted indole with a toluene­sulfonyl group bonded to the N atom. The benzyl group adopts a synclinal geometry with respect to the indole ring [dihedral angle = 59.95 (4)°], while the tolyl ring is oriented close to perpendicular to the indole ring, making a dihedral angle of 81.85 (3)°. The indole N atom exhibits a slight pyramidalization. International Union of Crystallography 2013-05-31 /pmc/articles/PMC3685113/ /pubmed/23795132 http://dx.doi.org/10.1107/S1600536813014001 Text en © Pozza Silveira et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pozza Silveira, Gustavo
Oliver, Allen G.
Noll, Bruce C.
5-Benz­yloxy-3-methyl-1-tosyl-1H-indole
title 5-Benz­yloxy-3-methyl-1-tosyl-1H-indole
title_full 5-Benz­yloxy-3-methyl-1-tosyl-1H-indole
title_fullStr 5-Benz­yloxy-3-methyl-1-tosyl-1H-indole
title_full_unstemmed 5-Benz­yloxy-3-methyl-1-tosyl-1H-indole
title_short 5-Benz­yloxy-3-methyl-1-tosyl-1H-indole
title_sort 5-benz­yloxy-3-methyl-1-tosyl-1h-indole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685113/
https://www.ncbi.nlm.nih.gov/pubmed/23795132
http://dx.doi.org/10.1107/S1600536813014001
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