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4-Cyano-1-methyl­pyridinium nitrate

The title mol­ecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an inter­penetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bis­ected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms i...

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Detalles Bibliográficos
Autores principales: McCormick, Cameron A., Nguyen, Vu D., Renfro, Heather E., Koplitz, Lynn V., Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685115/
https://www.ncbi.nlm.nih.gov/pubmed/23795134
http://dx.doi.org/10.1107/S1600536813014025
Descripción
Sumario:The title mol­ecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an inter­penetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bis­ected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms in addition to cation–cation C—H⋯N hydrogen bonds (ring H to cyano N) serve to link the sheets together. In each set of parallel layers, the cations and anions stack with short distances of 3.094 (2) (between aligned nitrate N and pyridine N atoms) and 3.057 (2) Å (between a nitrate O atom and the ring centroid). This motif is strikingly similar to the one that features in the isomeric salt 2-cyano-1-methyl­pyridinium nitrate.