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4-Cyano-1-methylpyridinium nitrate
The title molecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an interpenetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bisected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms i...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685115/ https://www.ncbi.nlm.nih.gov/pubmed/23795134 http://dx.doi.org/10.1107/S1600536813014025 |
Sumario: | The title molecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an interpenetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bisected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms in addition to cation–cation C—H⋯N hydrogen bonds (ring H to cyano N) serve to link the sheets together. In each set of parallel layers, the cations and anions stack with short distances of 3.094 (2) (between aligned nitrate N and pyridine N atoms) and 3.057 (2) Å (between a nitrate O atom and the ring centroid). This motif is strikingly similar to the one that features in the isomeric salt 2-cyano-1-methylpyridinium nitrate. |
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