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4-Cyano-1-methylpyridinium nitrate
The title molecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an interpenetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bisected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms i...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685115/ https://www.ncbi.nlm.nih.gov/pubmed/23795134 http://dx.doi.org/10.1107/S1600536813014025 |
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author | McCormick, Cameron A. Nguyen, Vu D. Renfro, Heather E. Koplitz, Lynn V. Mague, Joel T. |
author_facet | McCormick, Cameron A. Nguyen, Vu D. Renfro, Heather E. Koplitz, Lynn V. Mague, Joel T. |
author_sort | McCormick, Cameron A. |
collection | PubMed |
description | The title molecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an interpenetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bisected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms in addition to cation–cation C—H⋯N hydrogen bonds (ring H to cyano N) serve to link the sheets together. In each set of parallel layers, the cations and anions stack with short distances of 3.094 (2) (between aligned nitrate N and pyridine N atoms) and 3.057 (2) Å (between a nitrate O atom and the ring centroid). This motif is strikingly similar to the one that features in the isomeric salt 2-cyano-1-methylpyridinium nitrate. |
format | Online Article Text |
id | pubmed-3685115 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36851152013-06-21 4-Cyano-1-methylpyridinium nitrate McCormick, Cameron A. Nguyen, Vu D. Renfro, Heather E. Koplitz, Lynn V. Mague, Joel T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecular salt, C(7)H(7)N(2) (+)·NO(3) (−), displays an interpenetrating sheet structure parallel to a with each sheet containing nearly coplanar cations and anions, each ion being bisected by a crystallographic mirror plane. C—H⋯O hydrogen bonds involving both ring and methyl H atoms in addition to cation–cation C—H⋯N hydrogen bonds (ring H to cyano N) serve to link the sheets together. In each set of parallel layers, the cations and anions stack with short distances of 3.094 (2) (between aligned nitrate N and pyridine N atoms) and 3.057 (2) Å (between a nitrate O atom and the ring centroid). This motif is strikingly similar to the one that features in the isomeric salt 2-cyano-1-methylpyridinium nitrate. International Union of Crystallography 2013-05-31 /pmc/articles/PMC3685115/ /pubmed/23795134 http://dx.doi.org/10.1107/S1600536813014025 Text en © McCormick et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers McCormick, Cameron A. Nguyen, Vu D. Renfro, Heather E. Koplitz, Lynn V. Mague, Joel T. 4-Cyano-1-methylpyridinium nitrate |
title | 4-Cyano-1-methylpyridinium nitrate |
title_full | 4-Cyano-1-methylpyridinium nitrate |
title_fullStr | 4-Cyano-1-methylpyridinium nitrate |
title_full_unstemmed | 4-Cyano-1-methylpyridinium nitrate |
title_short | 4-Cyano-1-methylpyridinium nitrate |
title_sort | 4-cyano-1-methylpyridinium nitrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685115/ https://www.ncbi.nlm.nih.gov/pubmed/23795134 http://dx.doi.org/10.1107/S1600536813014025 |
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