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N,N′-Bis(4-hydroxyphenyl)pyridine-2,6-dicarboxamide dimethylformamide monosolvate
The molecular structure of the pyridine derivative, C(19)H(15)N(3)O(4)·C(3)H(7)NO, shows almost planar geometry with dihedral angles of 6.9 (1) and 13.4 (1)° between the pyridine ring and the two benzene rings. This conformation is stabilized by two intramolecular N—H⋯N(pyridine) bonds. In the cry...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685123/ https://www.ncbi.nlm.nih.gov/pubmed/23795142 http://dx.doi.org/10.1107/S1600536813013810 |
Sumario: | The molecular structure of the pyridine derivative, C(19)H(15)N(3)O(4)·C(3)H(7)NO, shows almost planar geometry with dihedral angles of 6.9 (1) and 13.4 (1)° between the pyridine ring and the two benzene rings. This conformation is stabilized by two intramolecular N—H⋯N(pyridine) bonds. In the crystal, strong O—H⋯O(carboxamide) and N—H⋯O(hydroxyphenyl) hydrogen bonds link the molecules, forming a three-dimensional structure. The dimethylformamide solvent molecules are not involved in the hydrogen bonding. The structure shows pseudosymmetry, but refinement in the space group Pbcn leads to significantly worse results and a disordered dimethylformamide molecule. |
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