2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]

In the title spiro-phosphazene derivative, C(33)H(46)N(9)OP(3), the phosphazene and six-membered N/O rings are in flattened chair and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 41.82 (4)°. In the crystal, weak C—H⋯O...

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Detalles Bibliográficos
Autores principales: Işıklan, Muhammet, Sonkaya, Ömer, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685126/
https://www.ncbi.nlm.nih.gov/pubmed/23795145
http://dx.doi.org/10.1107/S1600536813014220
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author Işıklan, Muhammet
Sonkaya, Ömer
Hökelek, Tuncer
author_facet Işıklan, Muhammet
Sonkaya, Ömer
Hökelek, Tuncer
author_sort Işıklan, Muhammet
collection PubMed
description In the title spiro-phosphazene derivative, C(33)H(46)N(9)OP(3), the phosphazene and six-membered N/O rings are in flattened chair and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 41.82 (4)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules related by translation along the a axis into chains. C—H⋯π inter­actions aggregate these chains into layers parallel to the ab plane.
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spelling pubmed-36851262013-06-21 2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine] Işıklan, Muhammet Sonkaya, Ömer Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title spiro-phosphazene derivative, C(33)H(46)N(9)OP(3), the phosphazene and six-membered N/O rings are in flattened chair and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 41.82 (4)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules related by translation along the a axis into chains. C—H⋯π inter­actions aggregate these chains into layers parallel to the ab plane. International Union of Crystallography 2013-05-31 /pmc/articles/PMC3685126/ /pubmed/23795145 http://dx.doi.org/10.1107/S1600536813014220 Text en © Işıklan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Işıklan, Muhammet
Sonkaya, Ömer
Hökelek, Tuncer
2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title 2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_full 2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_fullStr 2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_full_unstemmed 2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_short 2-(4-Methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1H,2H-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
title_sort 2-(4-methyl­pyridin-2-yl)-4′,4′,6′,6′-tetra­kis­(pyrrolidin-1-yl)-1h,2h-spiro­[naphtho­[1,2-e][1,3,2]oxaza­phosphinine-3,2′-[1,3,5,2,4,6]tri­aza­triphosphinine]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685126/
https://www.ncbi.nlm.nih.gov/pubmed/23795145
http://dx.doi.org/10.1107/S1600536813014220
work_keys_str_mv AT isıklanmuhammet 24methylpyridin2yl4466tetrakispyrrolidin1yl1h2hspironaphtho12e132oxazaphosphinine32135246triazatriphosphinine
AT sonkayaomer 24methylpyridin2yl4466tetrakispyrrolidin1yl1h2hspironaphtho12e132oxazaphosphinine32135246triazatriphosphinine
AT hokelektuncer 24methylpyridin2yl4466tetrakispyrrolidin1yl1h2hspironaphtho12e132oxazaphosphinine32135246triazatriphosphinine

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