Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides

We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.

Detalles Bibliográficos
Autores principales: Too, Pei Chui, Tnay, Ya Lin, Chiba, Shunsuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701382/
https://www.ncbi.nlm.nih.gov/pubmed/23843917
http://dx.doi.org/10.3762/bjoc.9.138
Descripción
Sumario:We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.

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