Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides

We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.

Detalles Bibliográficos
Autores principales: Too, Pei Chui, Tnay, Ya Lin, Chiba, Shunsuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701382/
https://www.ncbi.nlm.nih.gov/pubmed/23843917
http://dx.doi.org/10.3762/bjoc.9.138
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author Too, Pei Chui
Tnay, Ya Lin
Chiba, Shunsuke
author_facet Too, Pei Chui
Tnay, Ya Lin
Chiba, Shunsuke
author_sort Too, Pei Chui
collection PubMed
description We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
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spelling pubmed-37013822013-07-10 Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke Beilstein J Org Chem Letter We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen. Beilstein-Institut 2013-06-25 /pmc/articles/PMC3701382/ /pubmed/23843917 http://dx.doi.org/10.3762/bjoc.9.138 Text en Copyright © 2013, Too et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Too, Pei Chui
Tnay, Ya Lin
Chiba, Shunsuke
Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_full Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_fullStr Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_full_unstemmed Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_short Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
title_sort copper-catalyzed aerobic aliphatic c–h oxygenation with hydroperoxides
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701382/
https://www.ncbi.nlm.nih.gov/pubmed/23843917
http://dx.doi.org/10.3762/bjoc.9.138
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AT tnayyalin coppercatalyzedaerobicaliphaticchoxygenationwithhydroperoxides
AT chibashunsuke coppercatalyzedaerobicaliphaticchoxygenationwithhydroperoxides

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