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Establishing the concept of aza-[3 + 3] annulations using enones as a key expansion of this unified strategy in alkaloid synthesis

A successful enone version of an intramolecular aza-[3 + 3] annulation reaction is described here. Use of piperidinium trifluoroacetate salt as the catalyst and toluene as the solvent appears to be critical for a successful annulation. We also demonstrated for the first time that microwave irradiati...

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Detalles Bibliográficos
Autores principales: Gerasyuto, Aleksey I, Ma, Zhi-Xiong, Buchanan, Grant S, Hsung, Richard P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701412/
https://www.ncbi.nlm.nih.gov/pubmed/23843910
http://dx.doi.org/10.3762/bjoc.9.131

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