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Establishing the concept of aza-[3 + 3] annulations using enones as a key expansion of this unified strategy in alkaloid synthesis
A successful enone version of an intramolecular aza-[3 + 3] annulation reaction is described here. Use of piperidinium trifluoroacetate salt as the catalyst and toluene as the solvent appears to be critical for a successful annulation. We also demonstrated for the first time that microwave irradiati...
Autores principales: | Gerasyuto, Aleksey I, Ma, Zhi-Xiong, Buchanan, Grant S, Hsung, Richard P |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701412/ https://www.ncbi.nlm.nih.gov/pubmed/23843910 http://dx.doi.org/10.3762/bjoc.9.131 |
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