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Homolytic substitution at phosphorus for C–P bond formation in organic synthesis
Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents include diphosphines, chalcogenophosphines an...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701419/ https://www.ncbi.nlm.nih.gov/pubmed/23843922 http://dx.doi.org/10.3762/bjoc.9.143 |
| _version_ | 1782275638640508928 |
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| author | Yorimitsu, Hideki |
| author_facet | Yorimitsu, Hideki |
| author_sort | Yorimitsu, Hideki |
| collection | PubMed |
| description | Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents include diphosphines, chalcogenophosphines and stannylphosphines, which bear a weak P–heteroatom bond for homolysis. This article deals with two transformations, radical phosphination by addition across unsaturated C–C bonds and substitution of organic halides. |
| format | Online Article Text |
| id | pubmed-3701419 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37014192013-07-10 Homolytic substitution at phosphorus for C–P bond formation in organic synthesis Yorimitsu, Hideki Beilstein J Org Chem Review Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents include diphosphines, chalcogenophosphines and stannylphosphines, which bear a weak P–heteroatom bond for homolysis. This article deals with two transformations, radical phosphination by addition across unsaturated C–C bonds and substitution of organic halides. Beilstein-Institut 2013-06-28 /pmc/articles/PMC3701419/ /pubmed/23843922 http://dx.doi.org/10.3762/bjoc.9.143 Text en Copyright © 2013, Yorimitsu https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Review Yorimitsu, Hideki Homolytic substitution at phosphorus for C–P bond formation in organic synthesis |
| title | Homolytic substitution at phosphorus for C–P bond formation in organic synthesis |
| title_full | Homolytic substitution at phosphorus for C–P bond formation in organic synthesis |
| title_fullStr | Homolytic substitution at phosphorus for C–P bond formation in organic synthesis |
| title_full_unstemmed | Homolytic substitution at phosphorus for C–P bond formation in organic synthesis |
| title_short | Homolytic substitution at phosphorus for C–P bond formation in organic synthesis |
| title_sort | homolytic substitution at phosphorus for c–p bond formation in organic synthesis |
| topic | Review |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701419/ https://www.ncbi.nlm.nih.gov/pubmed/23843922 http://dx.doi.org/10.3762/bjoc.9.143 |
| work_keys_str_mv | AT yorimitsuhideki homolyticsubstitutionatphosphorusforcpbondformationinorganicsynthesis |