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Revealing water’s secrets: deuterium depleted water
BACKGROUND: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
BioMed Central
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3703265/ https://www.ncbi.nlm.nih.gov/pubmed/23773696 http://dx.doi.org/10.1186/1752-153X-7-103 |
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author | Goncharuk, Vladyslav V Kavitskaya, Alina A Romanyukina, Iryna Yu Loboda, Oleksandr A |
author_facet | Goncharuk, Vladyslav V Kavitskaya, Alina A Romanyukina, Iryna Yu Loboda, Oleksandr A |
author_sort | Goncharuk, Vladyslav V |
collection | PubMed |
description | BACKGROUND: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light) water at 4°C and 20°C are here presented. RESULTS: The obtained results show the important role of the deuterium in the properties of bulk water. At 4°C the lowest value of the kinematic viscosity (1.46 mm(2)/s) has been found for 96.5 ppm D/H ratio. The significant deviation in surface tension values has been observed in deuterium depleted water samples at the both temperature regimes. The experimental data provides direct evidence that density, surface tension and viscosity anomalies of water are caused by the presence of variable concentration of deuterium which leads to the formation of water clusters of different size and quantity. CONCLUSIONS: The investigated properties of light water reveal the origin of the water anomalies. The new theoretical model of cluster formation with account of isotope effect is proposed. |
format | Online Article Text |
id | pubmed-3703265 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | BioMed Central |
record_format | MEDLINE/PubMed |
spelling | pubmed-37032652013-07-10 Revealing water’s secrets: deuterium depleted water Goncharuk, Vladyslav V Kavitskaya, Alina A Romanyukina, Iryna Yu Loboda, Oleksandr A Chem Cent J Research Article BACKGROUND: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light) water at 4°C and 20°C are here presented. RESULTS: The obtained results show the important role of the deuterium in the properties of bulk water. At 4°C the lowest value of the kinematic viscosity (1.46 mm(2)/s) has been found for 96.5 ppm D/H ratio. The significant deviation in surface tension values has been observed in deuterium depleted water samples at the both temperature regimes. The experimental data provides direct evidence that density, surface tension and viscosity anomalies of water are caused by the presence of variable concentration of deuterium which leads to the formation of water clusters of different size and quantity. CONCLUSIONS: The investigated properties of light water reveal the origin of the water anomalies. The new theoretical model of cluster formation with account of isotope effect is proposed. BioMed Central 2013-06-17 /pmc/articles/PMC3703265/ /pubmed/23773696 http://dx.doi.org/10.1186/1752-153X-7-103 Text en Copyright © 2013 Goncharuk et al.; licensee Chemistry Central Ltd. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Goncharuk, Vladyslav V Kavitskaya, Alina A Romanyukina, Iryna Yu Loboda, Oleksandr A Revealing water’s secrets: deuterium depleted water |
title | Revealing water’s secrets: deuterium depleted water |
title_full | Revealing water’s secrets: deuterium depleted water |
title_fullStr | Revealing water’s secrets: deuterium depleted water |
title_full_unstemmed | Revealing water’s secrets: deuterium depleted water |
title_short | Revealing water’s secrets: deuterium depleted water |
title_sort | revealing water’s secrets: deuterium depleted water |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3703265/ https://www.ncbi.nlm.nih.gov/pubmed/23773696 http://dx.doi.org/10.1186/1752-153X-7-103 |
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