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Revealing water’s secrets: deuterium depleted water

BACKGROUND: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light...

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Autores principales: Goncharuk, Vladyslav V, Kavitskaya, Alina A, Romanyukina, Iryna Yu, Loboda, Oleksandr A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: BioMed Central 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3703265/
https://www.ncbi.nlm.nih.gov/pubmed/23773696
http://dx.doi.org/10.1186/1752-153X-7-103
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author Goncharuk, Vladyslav V
Kavitskaya, Alina A
Romanyukina, Iryna Yu
Loboda, Oleksandr A
author_facet Goncharuk, Vladyslav V
Kavitskaya, Alina A
Romanyukina, Iryna Yu
Loboda, Oleksandr A
author_sort Goncharuk, Vladyslav V
collection PubMed
description BACKGROUND: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light) water at 4°C and 20°C are here presented. RESULTS: The obtained results show the important role of the deuterium in the properties of bulk water. At 4°C the lowest value of the kinematic viscosity (1.46 mm(2)/s) has been found for 96.5 ppm D/H ratio. The significant deviation in surface tension values has been observed in deuterium depleted water samples at the both temperature regimes. The experimental data provides direct evidence that density, surface tension and viscosity anomalies of water are caused by the presence of variable concentration of deuterium which leads to the formation of water clusters of different size and quantity. CONCLUSIONS: The investigated properties of light water reveal the origin of the water anomalies. The new theoretical model of cluster formation with account of isotope effect is proposed.
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spelling pubmed-37032652013-07-10 Revealing water’s secrets: deuterium depleted water Goncharuk, Vladyslav V Kavitskaya, Alina A Romanyukina, Iryna Yu Loboda, Oleksandr A Chem Cent J Research Article BACKGROUND: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light) water at 4°C and 20°C are here presented. RESULTS: The obtained results show the important role of the deuterium in the properties of bulk water. At 4°C the lowest value of the kinematic viscosity (1.46 mm(2)/s) has been found for 96.5 ppm D/H ratio. The significant deviation in surface tension values has been observed in deuterium depleted water samples at the both temperature regimes. The experimental data provides direct evidence that density, surface tension and viscosity anomalies of water are caused by the presence of variable concentration of deuterium which leads to the formation of water clusters of different size and quantity. CONCLUSIONS: The investigated properties of light water reveal the origin of the water anomalies. The new theoretical model of cluster formation with account of isotope effect is proposed. BioMed Central 2013-06-17 /pmc/articles/PMC3703265/ /pubmed/23773696 http://dx.doi.org/10.1186/1752-153X-7-103 Text en Copyright © 2013 Goncharuk et al.; licensee Chemistry Central Ltd. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Goncharuk, Vladyslav V
Kavitskaya, Alina A
Romanyukina, Iryna Yu
Loboda, Oleksandr A
Revealing water’s secrets: deuterium depleted water
title Revealing water’s secrets: deuterium depleted water
title_full Revealing water’s secrets: deuterium depleted water
title_fullStr Revealing water’s secrets: deuterium depleted water
title_full_unstemmed Revealing water’s secrets: deuterium depleted water
title_short Revealing water’s secrets: deuterium depleted water
title_sort revealing water’s secrets: deuterium depleted water
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3703265/
https://www.ncbi.nlm.nih.gov/pubmed/23773696
http://dx.doi.org/10.1186/1752-153X-7-103
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