Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones

The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, wer...

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Autores principales: Shen, Hao-Yu, Ying, Li-Yan, Jiang, Hai-Liang, Judeh, Zaher M. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2007
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3714610/
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author Shen, Hao-Yu
Ying, Li-Yan
Jiang, Hai-Liang
Judeh, Zaher M. A.
author_facet Shen, Hao-Yu
Ying, Li-Yan
Jiang, Hai-Liang
Judeh, Zaher M. A.
author_sort Shen, Hao-Yu
collection PubMed
description The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF(6), [omim]BF(4) and [hmim]BF(4), comparing to traditional volatile organic solvent. The use of ionic liquids was found to enhance the catalytic properties of the catalysts used.
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spelling pubmed-37146102013-07-18 Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones Shen, Hao-Yu Ying, Li-Yan Jiang, Hai-Liang Judeh, Zaher M. A. Int J Mol Sci Full Research Paper The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF(6), [omim]BF(4) and [hmim]BF(4), comparing to traditional volatile organic solvent. The use of ionic liquids was found to enhance the catalytic properties of the catalysts used. Molecular Diversity Preservation International (MDPI) 2007-06-06 /pmc/articles/PMC3714610/ Text en © 2007 by MDPI Reproduction is permitted for noncommercial purposes.
spellingShingle Full Research Paper
Shen, Hao-Yu
Ying, Li-Yan
Jiang, Hai-Liang
Judeh, Zaher M. A.
Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
title Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
title_full Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
title_fullStr Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
title_full_unstemmed Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
title_short Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones
title_sort efficient copper-bisisoquinoline-based catalysts for selective aerobic oxidation of alcohols to aldehydes and ketones
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3714610/
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AT jianghailiang efficientcopperbisisoquinolinebasedcatalystsforselectiveaerobicoxidationofalcoholstoaldehydesandketones
AT judehzaherma efficientcopperbisisoquinolinebasedcatalystsforselectiveaerobicoxidationofalcoholstoaldehydesandketones

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