Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent

The retention of aliphatic hydrocarbons with polar groups has been compared in respect to the separation selectivity changes in reversed-phase high-performance liquid chromatography with C18 stationary phase type and binary water eluent composed of methanol, acetonitrile, or tetrahydrofuran as modif...

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Autores principales: Klimek-Turek, Anna, Misiołek, Beata, Dzido, Tadeusz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2013
Materias:
Original
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3723982/
https://www.ncbi.nlm.nih.gov/pubmed/23913977
http://dx.doi.org/10.1007/s10337-013-2489-4
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author Klimek-Turek, Anna
Misiołek, Beata
Dzido, Tadeusz H.
author_facet Klimek-Turek, Anna
Misiołek, Beata
Dzido, Tadeusz H.
author_sort Klimek-Turek, Anna
collection PubMed
description The retention of aliphatic hydrocarbons with polar groups has been compared in respect to the separation selectivity changes in reversed-phase high-performance liquid chromatography with C18 stationary phase type and binary water eluent composed of methanol, acetonitrile, or tetrahydrofuran as modifiers. The changes in separation selectivity when one modifier is replaced by another in the eluent is explained, taking into consideration molecular interactions of the solutes with components of the stationary phase region, i.e., extracted modifier, and ordering of the stationary phase by the modifier.
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spelling pubmed-37239822013-08-01 Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent Klimek-Turek, Anna Misiołek, Beata Dzido, Tadeusz H. Chromatographia Original The retention of aliphatic hydrocarbons with polar groups has been compared in respect to the separation selectivity changes in reversed-phase high-performance liquid chromatography with C18 stationary phase type and binary water eluent composed of methanol, acetonitrile, or tetrahydrofuran as modifiers. The changes in separation selectivity when one modifier is replaced by another in the eluent is explained, taking into consideration molecular interactions of the solutes with components of the stationary phase region, i.e., extracted modifier, and ordering of the stationary phase by the modifier. Springer Berlin Heidelberg 2013-06-09 2013 /pmc/articles/PMC3723982/ /pubmed/23913977 http://dx.doi.org/10.1007/s10337-013-2489-4 Text en © The Author(s) 2013 https://creativecommons.org/licenses/by/2.0/ Open AccessThis article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
spellingShingle Original
Klimek-Turek, Anna
Misiołek, Beata
Dzido, Tadeusz H.
Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent
title Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent
title_full Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent
title_fullStr Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent
title_full_unstemmed Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent
title_short Comparison of the Retention of Aliphatic Hydrocarbons with Polar Groups in RP-HPLC Systems with Different Modifiers of the Binary Eluent
title_sort comparison of the retention of aliphatic hydrocarbons with polar groups in rp-hplc systems with different modifiers of the binary eluent
topic Original
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3723982/
https://www.ncbi.nlm.nih.gov/pubmed/23913977
http://dx.doi.org/10.1007/s10337-013-2489-4
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