Cargando…

Liquid crystal self-templating approach to ultrastrong and tough biomimic composites

Materials with both high strength and toughness are in great demand for a wide range of applications, requiring strict design of ingredients and hierarchically ordered architecture from nano- to macro-scale. Nacre achieves such a target in the long natural evolution by alternative alignment of inorg...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Xiaozhen, Xu, Zhen, Liu, Zheng, Gao, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3734524/
https://www.ncbi.nlm.nih.gov/pubmed/23918042
http://dx.doi.org/10.1038/srep02374
Descripción
Sumario:Materials with both high strength and toughness are in great demand for a wide range of applications, requiring strict design of ingredients and hierarchically ordered architecture from nano- to macro-scale. Nacre achieves such a target in the long natural evolution by alternative alignment of inorganic nanoplatelets and biomacromolecules. To mimic nacre, various strategies were developed, approaching nacre-comparable performance in limited size. How to remarkably exceed nacre in both property and size is a key issue to further the advancement of composites. Here we present liquid crystal self-templating methodology to make the next generation of ultrastrong and tough nacre-mimics continuously. The hierarchically assembled composites show the highest tensile strength (652 MPa) among nacre mimics, five to eight times as high as that of nacre (80–135 MPa), and excellent ductility with toughness of 18 MJ m(−3), one to two orders of magnitude greater than that of nacre (0.1 ~ 1.8 MJ m(−3)).