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A full-sunlight-driven photocatalyst with super long-persistent energy storage ability

A major drawback of traditional photocatalysts like TiO(2) is that they can only work under illumination, and the light has to be UV. As a solution for this limitation, visible-light-driven energy storage photocatalysts have been developed in recent years. However, energy storage photocatalysts that...

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Detalles Bibliográficos
Autores principales: Li, Jie, Liu, Yuan, Zhu, Zhijian, Zhang, Guozhu, Zou, Tao, Zou, Zhijun, Zhang, Shunping, Zeng, Dawen, Xie, Changsheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740289/
https://www.ncbi.nlm.nih.gov/pubmed/23934407
http://dx.doi.org/10.1038/srep02409
Descripción
Sumario:A major drawback of traditional photocatalysts like TiO(2) is that they can only work under illumination, and the light has to be UV. As a solution for this limitation, visible-light-driven energy storage photocatalysts have been developed in recent years. However, energy storage photocatalysts that are full-sunlight-driven (UV-visible-NIR) and possess long-lasting energy storage ability are lacking. Here we report, a Pt-loaded and hydrogen-treated WO(3) that exhibits a strong absorption at full-sunlight spectrum (300–1,000 nm), and with a super-long energy storage time of more than 300 h to have formaldehyde degraded in dark. In this new material system, the hydrogen treated WO(3) functions as the light harvesting material and energy storage material simultaneously, while Pt mainly acts as the cocatalyst to have the energy storage effect displayed. The extraordinary full-spectrum absorption effect and long persistent energy storage ability make the material a potential solar-energy storage and an effective photocatalyst in practice.