Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads

Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor–acceptor–donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres an...

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Detalles Bibliográficos
Autores principales: Avinash, M B, Sandeepa, K V, Govindaraju, T
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740681/
https://www.ncbi.nlm.nih.gov/pubmed/23946856
http://dx.doi.org/10.3762/bjoc.9.178
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author Avinash, M B
Sandeepa, K V
Govindaraju, T
author_facet Avinash, M B
Sandeepa, K V
Govindaraju, T
author_sort Avinash, M B
collection PubMed
description Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor–acceptor–donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres and hierarchical helical bundles of triads are realized by modulating the chemical functionality of interlinking amino acids.
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spelling pubmed-37406812013-08-14 Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads Avinash, M B Sandeepa, K V Govindaraju, T Beilstein J Org Chem Letter Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor–acceptor–donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres and hierarchical helical bundles of triads are realized by modulating the chemical functionality of interlinking amino acids. Beilstein-Institut 2013-08-01 /pmc/articles/PMC3740681/ /pubmed/23946856 http://dx.doi.org/10.3762/bjoc.9.178 Text en Copyright © 2013, Avinash et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Avinash, M B
Sandeepa, K V
Govindaraju, T
Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_full Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_fullStr Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_full_unstemmed Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_short Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
title_sort molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740681/
https://www.ncbi.nlm.nih.gov/pubmed/23946856
http://dx.doi.org/10.3762/bjoc.9.178
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