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Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Scholarly Research Network
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767372/ https://www.ncbi.nlm.nih.gov/pubmed/24052854 http://dx.doi.org/10.5402/2012/873046 |
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author | Adewuyi, Adewale Göpfert, Andrea Wolff, Thomas Rao, B. V. S. K. Prasad, R. B. N. |
author_facet | Adewuyi, Adewale Göpfert, Andrea Wolff, Thomas Rao, B. V. S. K. Prasad, R. B. N. |
author_sort | Adewuyi, Adewale |
collection | PubMed |
description | The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed of Hura crepitans was characterized by an iodine value of 120.10 ± 0.70 g Iodine/100 g and a saponification number of 210.10 ± 0.40 mg KOH/g with the dominant fatty acid being C18:2 (52.8 ± 0.10%). The epoxidised fatty acid methyl esters prepared from the oil were used to synthesise the azidohydrin with a yield of 91.20%. The progress of the reaction was monitored and confirmed using FTIR and NMR. This showed the seed oil of Hura crepitans as a renewable resource that can be used to make valuable industrial and domestic products. |
format | Online Article Text |
id | pubmed-3767372 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Scholarly Research Network |
record_format | MEDLINE/PubMed |
spelling | pubmed-37673722013-09-19 Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development Adewuyi, Adewale Göpfert, Andrea Wolff, Thomas Rao, B. V. S. K. Prasad, R. B. N. ISRN Org Chem Research Article The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed of Hura crepitans was characterized by an iodine value of 120.10 ± 0.70 g Iodine/100 g and a saponification number of 210.10 ± 0.40 mg KOH/g with the dominant fatty acid being C18:2 (52.8 ± 0.10%). The epoxidised fatty acid methyl esters prepared from the oil were used to synthesise the azidohydrin with a yield of 91.20%. The progress of the reaction was monitored and confirmed using FTIR and NMR. This showed the seed oil of Hura crepitans as a renewable resource that can be used to make valuable industrial and domestic products. International Scholarly Research Network 2012-11-06 /pmc/articles/PMC3767372/ /pubmed/24052854 http://dx.doi.org/10.5402/2012/873046 Text en Copyright © 2012 Adewale Adewuyi et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Adewuyi, Adewale Göpfert, Andrea Wolff, Thomas Rao, B. V. S. K. Prasad, R. B. N. Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development |
title | Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development |
title_full | Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development |
title_fullStr | Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development |
title_full_unstemmed | Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development |
title_short | Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development |
title_sort | synthesis of azidohydrin from hura crepitans seed oil: a renewable resource for oleochemical industry and sustainable development |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767372/ https://www.ncbi.nlm.nih.gov/pubmed/24052854 http://dx.doi.org/10.5402/2012/873046 |
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