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Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development

The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed o...

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Autores principales: Adewuyi, Adewale, Göpfert, Andrea, Wolff, Thomas, Rao, B. V. S. K., Prasad, R. B. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Scholarly Research Network 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767372/
https://www.ncbi.nlm.nih.gov/pubmed/24052854
http://dx.doi.org/10.5402/2012/873046
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author Adewuyi, Adewale
Göpfert, Andrea
Wolff, Thomas
Rao, B. V. S. K.
Prasad, R. B. N.
author_facet Adewuyi, Adewale
Göpfert, Andrea
Wolff, Thomas
Rao, B. V. S. K.
Prasad, R. B. N.
author_sort Adewuyi, Adewale
collection PubMed
description The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed of Hura crepitans was characterized by an iodine value of 120.10 ± 0.70 g Iodine/100 g and a saponification number of 210.10 ± 0.40 mg KOH/g with the dominant fatty acid being C18:2 (52.8 ± 0.10%). The epoxidised fatty acid methyl esters prepared from the oil were used to synthesise the azidohydrin with a yield of 91.20%. The progress of the reaction was monitored and confirmed using FTIR and NMR. This showed the seed oil of Hura crepitans as a renewable resource that can be used to make valuable industrial and domestic products.
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spelling pubmed-37673722013-09-19 Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development Adewuyi, Adewale Göpfert, Andrea Wolff, Thomas Rao, B. V. S. K. Prasad, R. B. N. ISRN Org Chem Research Article The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed of Hura crepitans was characterized by an iodine value of 120.10 ± 0.70 g Iodine/100 g and a saponification number of 210.10 ± 0.40 mg KOH/g with the dominant fatty acid being C18:2 (52.8 ± 0.10%). The epoxidised fatty acid methyl esters prepared from the oil were used to synthesise the azidohydrin with a yield of 91.20%. The progress of the reaction was monitored and confirmed using FTIR and NMR. This showed the seed oil of Hura crepitans as a renewable resource that can be used to make valuable industrial and domestic products. International Scholarly Research Network 2012-11-06 /pmc/articles/PMC3767372/ /pubmed/24052854 http://dx.doi.org/10.5402/2012/873046 Text en Copyright © 2012 Adewale Adewuyi et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Adewuyi, Adewale
Göpfert, Andrea
Wolff, Thomas
Rao, B. V. S. K.
Prasad, R. B. N.
Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
title Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
title_full Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
title_fullStr Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
title_full_unstemmed Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
title_short Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development
title_sort synthesis of azidohydrin from hura crepitans seed oil: a renewable resource for oleochemical industry and sustainable development
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767372/
https://www.ncbi.nlm.nih.gov/pubmed/24052854
http://dx.doi.org/10.5402/2012/873046
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