Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons

A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m(2)/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C(3)H(8), and C(2)H(6) over CH(4) as IAST prediction. Furthermore, we explore th...

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Detalles Bibliográficos
Autores principales: Ma, Heping, Ren, Hao, Meng, Shuang, Sun, Fuxing, Zhu, Guangshan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767950/
https://www.ncbi.nlm.nih.gov/pubmed/24018972
http://dx.doi.org/10.1038/srep02611
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author Ma, Heping
Ren, Hao
Meng, Shuang
Sun, Fuxing
Zhu, Guangshan
author_facet Ma, Heping
Ren, Hao
Meng, Shuang
Sun, Fuxing
Zhu, Guangshan
author_sort Ma, Heping
collection PubMed
description A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m(2)/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C(3)H(8), and C(2)H(6) over CH(4) as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions.
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spelling pubmed-37679502013-09-11 Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons Ma, Heping Ren, Hao Meng, Shuang Sun, Fuxing Zhu, Guangshan Sci Rep Article A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m(2)/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C(3)H(8), and C(2)H(6) over CH(4) as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions. Nature Publishing Group 2013-09-10 /pmc/articles/PMC3767950/ /pubmed/24018972 http://dx.doi.org/10.1038/srep02611 Text en Copyright © 2013, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-nd/3.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported License. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/3.0/
spellingShingle Article
Ma, Heping
Ren, Hao
Meng, Shuang
Sun, Fuxing
Zhu, Guangshan
Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
title Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
title_full Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
title_fullStr Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
title_full_unstemmed Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
title_short Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
title_sort novel porphyrinic porous organic frameworks for high performance separation of small hydrocarbons
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767950/
https://www.ncbi.nlm.nih.gov/pubmed/24018972
http://dx.doi.org/10.1038/srep02611
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