10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide

The title compound, C(26)H(24)BF(2)N(3)O, comprises a boron–dipyrromethene (BODIPY) framework and a phenolic Schiff base substituent group. The BODIPY unit is close to planar [maximum deviation from the least-squares plane = 0.040 (3) Å], and forms a dihedral angle of 80.38 (13)° with the meso-subst...

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Autor principal: Li, Zhensheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770354/
https://www.ncbi.nlm.nih.gov/pubmed/24046639
http://dx.doi.org/10.1107/S1600536813015523
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author Li, Zhensheng
author_facet Li, Zhensheng
author_sort Li, Zhensheng
collection PubMed
description The title compound, C(26)H(24)BF(2)N(3)O, comprises a boron–dipyrromethene (BODIPY) framework and a phenolic Schiff base substituent group. The BODIPY unit is close to planar [maximum deviation from the least-squares plane = 0.040 (3) Å], and forms a dihedral angle of 80.38 (13)° with the meso-substituent phenyl ring and an angle of 56.57 (13)° with the phenolic ring in the extended substituent chain. An intra­molecular O—H⋯N hydrogen bond is formed between the phenolic hydroxyl group and the Schiff base N-atom. The crystal studied was a non-merohedral twin with a BASF factor of 0.447 (3) for the two components.
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spelling pubmed-37703542013-09-17 10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide Li, Zhensheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(24)BF(2)N(3)O, comprises a boron–dipyrromethene (BODIPY) framework and a phenolic Schiff base substituent group. The BODIPY unit is close to planar [maximum deviation from the least-squares plane = 0.040 (3) Å], and forms a dihedral angle of 80.38 (13)° with the meso-substituent phenyl ring and an angle of 56.57 (13)° with the phenolic ring in the extended substituent chain. An intra­molecular O—H⋯N hydrogen bond is formed between the phenolic hydroxyl group and the Schiff base N-atom. The crystal studied was a non-merohedral twin with a BASF factor of 0.447 (3) for the two components. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770354/ /pubmed/24046639 http://dx.doi.org/10.1107/S1600536813015523 Text en © Zhensheng Li 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhensheng
10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
title 10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
title_full 10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
title_fullStr 10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
title_full_unstemmed 10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
title_short 10-{4-[(2-Hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5H-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
title_sort 10-{4-[(2-hy­droxy­benzyl­idene)amino]­phen­yl}-5,5-di­fluoro-1,3,7,9-tetra­methyl-5h-di­pyrrolo­[1,2-c:2′,1′-f][1,3,2]di­aza­borinin-4-ium-5-uide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770354/
https://www.ncbi.nlm.nih.gov/pubmed/24046639
http://dx.doi.org/10.1107/S1600536813015523
work_keys_str_mv AT lizhensheng 1042hydroxybenzylideneaminophenyl55difluoro1379tetramethyl5hdipyrrolo12c21f132diazaborinin4ium5uide

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