4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine

In the title compound, C(12)H(10)N(4)O(2), the dihedral angle between the aromatic rings is 43.18 (16)°. The nitro group is rotated from its attached ring by 7.8 (2)° and a short intra­molecular N—H⋯N contact occurs. In the crystal, the mol­ecules are linked by N—H⋯N and C—H⋯O hydrogen bonds, genera...

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Detalles Bibliográficos
Autores principales: Liu, Guang-Lin, Sun, Jun, Zhang, Jing-Chao, Mei, Jie, Guo, Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770355/
https://www.ncbi.nlm.nih.gov/pubmed/24046640
http://dx.doi.org/10.1107/S1600536813015481
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author Liu, Guang-Lin
Sun, Jun
Zhang, Jing-Chao
Mei, Jie
Guo, Cheng
author_facet Liu, Guang-Lin
Sun, Jun
Zhang, Jing-Chao
Mei, Jie
Guo, Cheng
author_sort Liu, Guang-Lin
collection PubMed
description In the title compound, C(12)H(10)N(4)O(2), the dihedral angle between the aromatic rings is 43.18 (16)°. The nitro group is rotated from its attached ring by 7.8 (2)° and a short intra­molecular N—H⋯N contact occurs. In the crystal, the mol­ecules are linked by N—H⋯N and C—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-37703552013-09-17 4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine Liu, Guang-Lin Sun, Jun Zhang, Jing-Chao Mei, Jie Guo, Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(10)N(4)O(2), the dihedral angle between the aromatic rings is 43.18 (16)°. The nitro group is rotated from its attached ring by 7.8 (2)° and a short intra­molecular N—H⋯N contact occurs. In the crystal, the mol­ecules are linked by N—H⋯N and C—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770355/ /pubmed/24046640 http://dx.doi.org/10.1107/S1600536813015481 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Guang-Lin
Sun, Jun
Zhang, Jing-Chao
Mei, Jie
Guo, Cheng
4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
title 4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
title_full 4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
title_fullStr 4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
title_full_unstemmed 4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
title_short 4-Nitro-N^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
title_sort 4-nitro-n^2^-(pyridin-4-ylmethylidene)benzene-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770355/
https://www.ncbi.nlm.nih.gov/pubmed/24046640
http://dx.doi.org/10.1107/S1600536813015481
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