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rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine
In the title racemic Schiff base ligand, C(20)H(20)Cl(2)N(2), which was prepared by the condensation of 2-chlorobenzaldehyde and cyclohexane-1,2-diamine, the cyclohexane ring adopts a chair conformation and the dihedral angle between the aromatic rings of the 2-chlorophenyl substituent groups i...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770357/ https://www.ncbi.nlm.nih.gov/pubmed/24046642 http://dx.doi.org/10.1107/S1600536813014554 |
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author | Warad, Ismail Al-Noaimi, Mousa Haddad, Salim F. Al-Demeri, Yasmin Hammouti, Belkheir |
author_facet | Warad, Ismail Al-Noaimi, Mousa Haddad, Salim F. Al-Demeri, Yasmin Hammouti, Belkheir |
author_sort | Warad, Ismail |
collection | PubMed |
description | In the title racemic Schiff base ligand, C(20)H(20)Cl(2)N(2), which was prepared by the condensation of 2-chlorobenzaldehyde and cyclohexane-1,2-diamine, the cyclohexane ring adopts a chair conformation and the dihedral angle between the aromatic rings of the 2-chlorophenyl substituent groups is 62.52 (8)°. In the structure, there are two short intramolecular methine C—H⋯Cl interactions [C⋯Cl = 3.066 (2) and 3.076 (3) Å], and in the crystal there are also weak intermolecular aromatic C—H⋯Cl [3.464 (3), 3.553 (3) and 3.600 (3) Å] and Cl⋯Cl [3.557 (3) and 3.891 (3) Å] contacts. |
format | Online Article Text |
id | pubmed-3770357 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37703572013-09-17 rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine Warad, Ismail Al-Noaimi, Mousa Haddad, Salim F. Al-Demeri, Yasmin Hammouti, Belkheir Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title racemic Schiff base ligand, C(20)H(20)Cl(2)N(2), which was prepared by the condensation of 2-chlorobenzaldehyde and cyclohexane-1,2-diamine, the cyclohexane ring adopts a chair conformation and the dihedral angle between the aromatic rings of the 2-chlorophenyl substituent groups is 62.52 (8)°. In the structure, there are two short intramolecular methine C—H⋯Cl interactions [C⋯Cl = 3.066 (2) and 3.076 (3) Å], and in the crystal there are also weak intermolecular aromatic C—H⋯Cl [3.464 (3), 3.553 (3) and 3.600 (3) Å] and Cl⋯Cl [3.557 (3) and 3.891 (3) Å] contacts. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770357/ /pubmed/24046642 http://dx.doi.org/10.1107/S1600536813014554 Text en © Warad et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Warad, Ismail Al-Noaimi, Mousa Haddad, Salim F. Al-Demeri, Yasmin Hammouti, Belkheir rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
title |
rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
title_full |
rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
title_fullStr |
rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
title_full_unstemmed |
rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
title_short |
rac-(E,E)-N,N′-Bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
title_sort | rac-(e,e)-n,n′-bis(2-chlorobenzylidene)cyclohexane-1,2-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770357/ https://www.ncbi.nlm.nih.gov/pubmed/24046642 http://dx.doi.org/10.1107/S1600536813014554 |
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