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rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine

In the title racemic Schiff base ligand, C(20)H(20)Cl(2)N(2), which was prepared by the condensation of 2-chloro­benzaldehyde and cyclo­hexane-1,2-di­amine, the cyclo­hexane ring adopts a chair conformation and the dihedral angle between the aromatic rings of the 2-chloro­phenyl substituent groups i...

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Autores principales: Warad, Ismail, Al-Noaimi, Mousa, Haddad, Salim F., Al-Demeri, Yasmin, Hammouti, Belkheir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770357/
https://www.ncbi.nlm.nih.gov/pubmed/24046642
http://dx.doi.org/10.1107/S1600536813014554
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author Warad, Ismail
Al-Noaimi, Mousa
Haddad, Salim F.
Al-Demeri, Yasmin
Hammouti, Belkheir
author_facet Warad, Ismail
Al-Noaimi, Mousa
Haddad, Salim F.
Al-Demeri, Yasmin
Hammouti, Belkheir
author_sort Warad, Ismail
collection PubMed
description In the title racemic Schiff base ligand, C(20)H(20)Cl(2)N(2), which was prepared by the condensation of 2-chloro­benzaldehyde and cyclo­hexane-1,2-di­amine, the cyclo­hexane ring adopts a chair conformation and the dihedral angle between the aromatic rings of the 2-chloro­phenyl substituent groups is 62.52 (8)°. In the structure, there are two short intra­molecular methine C—H⋯Cl inter­actions [C⋯Cl = 3.066 (2) and 3.076 (3) Å], and in the crystal there are also weak inter­molecular aromatic C—H⋯Cl [3.464 (3), 3.553 (3) and 3.600 (3) Å] and Cl⋯Cl [3.557 (3) and 3.891 (3) Å] contacts.
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spelling pubmed-37703572013-09-17 rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine Warad, Ismail Al-Noaimi, Mousa Haddad, Salim F. Al-Demeri, Yasmin Hammouti, Belkheir Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title racemic Schiff base ligand, C(20)H(20)Cl(2)N(2), which was prepared by the condensation of 2-chloro­benzaldehyde and cyclo­hexane-1,2-di­amine, the cyclo­hexane ring adopts a chair conformation and the dihedral angle between the aromatic rings of the 2-chloro­phenyl substituent groups is 62.52 (8)°. In the structure, there are two short intra­molecular methine C—H⋯Cl inter­actions [C⋯Cl = 3.066 (2) and 3.076 (3) Å], and in the crystal there are also weak inter­molecular aromatic C—H⋯Cl [3.464 (3), 3.553 (3) and 3.600 (3) Å] and Cl⋯Cl [3.557 (3) and 3.891 (3) Å] contacts. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770357/ /pubmed/24046642 http://dx.doi.org/10.1107/S1600536813014554 Text en © Warad et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Warad, Ismail
Al-Noaimi, Mousa
Haddad, Salim F.
Al-Demeri, Yasmin
Hammouti, Belkheir
rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
title rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
title_full rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
title_fullStr rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
title_full_unstemmed rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
title_short rac-(E,E)-N,N′-Bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
title_sort rac-(e,e)-n,n′-bis(2-chloro­benzyl­idene)cyclo­hexane-1,2-di­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770357/
https://www.ncbi.nlm.nih.gov/pubmed/24046642
http://dx.doi.org/10.1107/S1600536813014554
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