2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate

In the title hydrated mol­ecular salt, C(12)H(14)N(2)S(2) (2+)·2Cl(−)·2H(2)O, the dihedral angle between the benzene rings in the dication is 9.03 (17)° and the C—S—S—C torsion angle is 96.8 (2)°. The crystal packing can be described as alternating organic and anionic water layers lying parallel to...

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Autores principales: Bouchareb, Hasna, Boudraa, Mhamed, Bouacida, Sofiane, Merazig, Hocin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770359/
https://www.ncbi.nlm.nih.gov/pubmed/24046644
http://dx.doi.org/10.1107/S1600536813015742
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author Bouchareb, Hasna
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocin
author_facet Bouchareb, Hasna
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocin
author_sort Bouchareb, Hasna
collection PubMed
description In the title hydrated mol­ecular salt, C(12)H(14)N(2)S(2) (2+)·2Cl(−)·2H(2)O, the dihedral angle between the benzene rings in the dication is 9.03 (17)° and the C—S—S—C torsion angle is 96.8 (2)°. The crystal packing can be described as alternating organic and anionic water layers lying parallel to (100), which are linked by N—H⋯Cl and N—H⋯O hydrogen bonds. O—H⋯Cl hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid separation = 3.730 (3) Å] are also observed.
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spelling pubmed-37703592013-09-17 2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate Bouchareb, Hasna Boudraa, Mhamed Bouacida, Sofiane Merazig, Hocin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated mol­ecular salt, C(12)H(14)N(2)S(2) (2+)·2Cl(−)·2H(2)O, the dihedral angle between the benzene rings in the dication is 9.03 (17)° and the C—S—S—C torsion angle is 96.8 (2)°. The crystal packing can be described as alternating organic and anionic water layers lying parallel to (100), which are linked by N—H⋯Cl and N—H⋯O hydrogen bonds. O—H⋯Cl hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid separation = 3.730 (3) Å] are also observed. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770359/ /pubmed/24046644 http://dx.doi.org/10.1107/S1600536813015742 Text en © Bouchareb et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bouchareb, Hasna
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocin
2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate
title 2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate
title_full 2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate
title_fullStr 2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate
title_full_unstemmed 2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate
title_short 2,2′-(Disulfanedi­yl)dianilinium dichloride dihydrate
title_sort 2,2′-(disulfanedi­yl)dianilinium dichloride dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770359/
https://www.ncbi.nlm.nih.gov/pubmed/24046644
http://dx.doi.org/10.1107/S1600536813015742
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AT boudraamhamed 22disulfanediyldianiliniumdichloridedihydrate
AT bouacidasofiane 22disulfanediyldianiliniumdichloridedihydrate
AT merazighocin 22disulfanediyldianiliniumdichloridedihydrate

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