Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)

The title compound, C(4)H(8)O(4)Te, crystallized from a solution of Te(4+) in ethyl­ene glycol. The Te(IV) atom is in a distorted seesaw coordination defined by four O atoms from two different ethyl­eneglycate ligands. The C atoms of the ethyl­eneglycate ligands are disorderd over two positions, wit...

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Autores principales: Brooks, Neil R., Wu, Minxian, Van Meervelt, Luc, Binnemans, Koen, Fransaer, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770360/
https://www.ncbi.nlm.nih.gov/pubmed/24046645
http://dx.doi.org/10.1107/S1600536813015687
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author Brooks, Neil R.
Wu, Minxian
Van Meervelt, Luc
Binnemans, Koen
Fransaer, Jan
author_facet Brooks, Neil R.
Wu, Minxian
Van Meervelt, Luc
Binnemans, Koen
Fransaer, Jan
author_sort Brooks, Neil R.
collection PubMed
description The title compound, C(4)H(8)O(4)Te, crystallized from a solution of Te(4+) in ethyl­ene glycol. The Te(IV) atom is in a distorted seesaw coordination defined by four O atoms from two different ethyl­eneglycate ligands. The C atoms of the ethyl­eneglycate ligands are disorderd over two positions, with population parameters of 50.3 (6) and 49.7 (6)% indicating a statistical distribution. Due to the possibility to transform the primitive monoclinic unit cell into a metrically ortho­rhom­bic C unit cell, the data are twinned and were refined with the twin law -100/0-10/101 with the relative scale factor refining to 1.82 (4)% for the minor component.
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spelling pubmed-37703602013-09-17 Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV) Brooks, Neil R. Wu, Minxian Van Meervelt, Luc Binnemans, Koen Fransaer, Jan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(4)H(8)O(4)Te, crystallized from a solution of Te(4+) in ethyl­ene glycol. The Te(IV) atom is in a distorted seesaw coordination defined by four O atoms from two different ethyl­eneglycate ligands. The C atoms of the ethyl­eneglycate ligands are disorderd over two positions, with population parameters of 50.3 (6) and 49.7 (6)% indicating a statistical distribution. Due to the possibility to transform the primitive monoclinic unit cell into a metrically ortho­rhom­bic C unit cell, the data are twinned and were refined with the twin law -100/0-10/101 with the relative scale factor refining to 1.82 (4)% for the minor component. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770360/ /pubmed/24046645 http://dx.doi.org/10.1107/S1600536813015687 Text en © Brooks et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Brooks, Neil R.
Wu, Minxian
Van Meervelt, Luc
Binnemans, Koen
Fransaer, Jan
Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)
title Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)
title_full Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)
title_fullStr Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)
title_full_unstemmed Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)
title_short Bis(ethyl­eneglycolato-κ(2) O,O′)tellurium(IV)
title_sort bis(ethyl­eneglycolato-κ(2) o,o′)tellurium(iv)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770360/
https://www.ncbi.nlm.nih.gov/pubmed/24046645
http://dx.doi.org/10.1107/S1600536813015687
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AT binnemanskoen bisethyleneglycolatok2ootelluriumiv
AT fransaerjan bisethyleneglycolatok2ootelluriumiv

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