2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol

The title compound, C(14)H(11)N(3)O(5), is a Schiff base that adopts the enol–imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 37.4 (3)° and the dihedral angles between the nitro groups and their attached rings are 4.0 (6) and 46.2 (8)°. The mol­ecular struc...

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Autores principales: Tanak, Hasan, Toğurman, Ferhat, Kalecik, Sedanur, Dege, Necmi, Yavuz, Metin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770363/
https://www.ncbi.nlm.nih.gov/pubmed/24046648
http://dx.doi.org/10.1107/S1600536813015407
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author Tanak, Hasan
Toğurman, Ferhat
Kalecik, Sedanur
Dege, Necmi
Yavuz, Metin
author_facet Tanak, Hasan
Toğurman, Ferhat
Kalecik, Sedanur
Dege, Necmi
Yavuz, Metin
author_sort Tanak, Hasan
collection PubMed
description The title compound, C(14)H(11)N(3)O(5), is a Schiff base that adopts the enol–imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 37.4 (3)° and the dihedral angles between the nitro groups and their attached rings are 4.0 (6) and 46.2 (8)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O interactions, forming a two-dimensional network parallel to the bc plane.
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spelling pubmed-37703632013-09-17 2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol Tanak, Hasan Toğurman, Ferhat Kalecik, Sedanur Dege, Necmi Yavuz, Metin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)N(3)O(5), is a Schiff base that adopts the enol–imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 37.4 (3)° and the dihedral angles between the nitro groups and their attached rings are 4.0 (6) and 46.2 (8)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O interactions, forming a two-dimensional network parallel to the bc plane. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3770363/ /pubmed/24046648 http://dx.doi.org/10.1107/S1600536813015407 Text en © Tanak et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tanak, Hasan
Toğurman, Ferhat
Kalecik, Sedanur
Dege, Necmi
Yavuz, Metin
2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
title 2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_full 2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_fullStr 2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_full_unstemmed 2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_short 2-{(E)-[(2-Methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_sort 2-{(e)-[(2-methyl-3-nitro­phen­yl)imino]­meth­yl}-4-nitro­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770363/
https://www.ncbi.nlm.nih.gov/pubmed/24046648
http://dx.doi.org/10.1107/S1600536813015407
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