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(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarbonitrile
The title compound, C(7)H(8)N(2)O(2), formed by dehydration of the corresponding dicarboxamide, crystallizes as rectangular prisms. The molecules have a C (2) axis of symmetry through the C atom bearing the methyl groups and the mid-point of the ring C—C bond, and the 1,3-dioxolane ring adopts the...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770379/ https://www.ncbi.nlm.nih.gov/pubmed/24046664 http://dx.doi.org/10.1107/S1600536813015973 |
Sumario: | The title compound, C(7)H(8)N(2)O(2), formed by dehydration of the corresponding dicarboxamide, crystallizes as rectangular prisms. The molecules have a C (2) axis of symmetry through the C atom bearing the methyl groups and the mid-point of the ring C—C bond, and the 1,3-dioxolane ring adopts the extreme twist conformation of the two possible with this symmetry. This brings the two nitrile groups nearest to a linear arrangement when the molecule is viewed along the ring C—C bond. The correct absolute configuration of the molecule was defined by that of the original starting material, (2R,3R)-tartaric acid. The packing is largely controlled by a number of C—H⋯N interactions. |
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