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Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate

The title compound, C(25)H(20)N(2)O(2), crystallized with two mol­ecules in the asymmetric unit, in one of which the atoms of the terminal propenyl group are disordered over two sets of sites, with a refined occupancy ratio of 0.870 (4):0.130 (4). The central imidazole ring makes dihedral angles of...

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Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Marzouk, Adel A., Abdelhamid, Antar A., Santoyo-Gonzalez, Francisco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770380/
https://www.ncbi.nlm.nih.gov/pubmed/24046665
http://dx.doi.org/10.1107/S160053681301619X
Descripción
Sumario:The title compound, C(25)H(20)N(2)O(2), crystallized with two mol­ecules in the asymmetric unit, in one of which the atoms of the terminal propenyl group are disordered over two sets of sites, with a refined occupancy ratio of 0.870 (4):0.130 (4). The central imidazole ring makes dihedral angles of 25.51 (11), 40.73 (11) and 27.36 (11)° with the three pendant rings in one molecule and 22.56 (10), 60.72 (10) and 5.85 (10)° in the other. In the crystal, mol­ecules are linked by N—H⋯N and C—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features C—H⋯π inter­actions and π–π stacking [centroid–centroid distances = 3.8834 (18) and 3.9621 (17) Å] inter­actions.