Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate

The title compound, C(25)H(20)N(2)O(2), crystallized with two mol­ecules in the asymmetric unit, in one of which the atoms of the terminal propenyl group are disordered over two sets of sites, with a refined occupancy ratio of 0.870 (4):0.130 (4). The central imidazole ring makes dihedral angles of...

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Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Marzouk, Adel A., Abdelhamid, Antar A., Santoyo-Gonzalez, Francisco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770380/
https://www.ncbi.nlm.nih.gov/pubmed/24046665
http://dx.doi.org/10.1107/S160053681301619X
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author Mohamed, Shaaban K.
Akkurt, Mehmet
Marzouk, Adel A.
Abdelhamid, Antar A.
Santoyo-Gonzalez, Francisco
author_facet Mohamed, Shaaban K.
Akkurt, Mehmet
Marzouk, Adel A.
Abdelhamid, Antar A.
Santoyo-Gonzalez, Francisco
author_sort Mohamed, Shaaban K.
collection PubMed
description The title compound, C(25)H(20)N(2)O(2), crystallized with two mol­ecules in the asymmetric unit, in one of which the atoms of the terminal propenyl group are disordered over two sets of sites, with a refined occupancy ratio of 0.870 (4):0.130 (4). The central imidazole ring makes dihedral angles of 25.51 (11), 40.73 (11) and 27.36 (11)° with the three pendant rings in one molecule and 22.56 (10), 60.72 (10) and 5.85 (10)° in the other. In the crystal, mol­ecules are linked by N—H⋯N and C—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features C—H⋯π inter­actions and π–π stacking [centroid–centroid distances = 3.8834 (18) and 3.9621 (17) Å] inter­actions.
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spelling pubmed-37703802013-09-17 Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate Mohamed, Shaaban K. Akkurt, Mehmet Marzouk, Adel A. Abdelhamid, Antar A. Santoyo-Gonzalez, Francisco Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(20)N(2)O(2), crystallized with two mol­ecules in the asymmetric unit, in one of which the atoms of the terminal propenyl group are disordered over two sets of sites, with a refined occupancy ratio of 0.870 (4):0.130 (4). The central imidazole ring makes dihedral angles of 25.51 (11), 40.73 (11) and 27.36 (11)° with the three pendant rings in one molecule and 22.56 (10), 60.72 (10) and 5.85 (10)° in the other. In the crystal, mol­ecules are linked by N—H⋯N and C—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features C—H⋯π inter­actions and π–π stacking [centroid–centroid distances = 3.8834 (18) and 3.9621 (17) Å] inter­actions. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3770380/ /pubmed/24046665 http://dx.doi.org/10.1107/S160053681301619X Text en © Mohamed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohamed, Shaaban K.
Akkurt, Mehmet
Marzouk, Adel A.
Abdelhamid, Antar A.
Santoyo-Gonzalez, Francisco
Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate
title Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate
title_full Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate
title_fullStr Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate
title_full_unstemmed Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate
title_short Prop-2-en-1-yl 4-(4,5-diphenyl-1H-imidazol-2-yl)benzoate
title_sort prop-2-en-1-yl 4-(4,5-diphenyl-1h-imidazol-2-yl)benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770380/
https://www.ncbi.nlm.nih.gov/pubmed/24046665
http://dx.doi.org/10.1107/S160053681301619X
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