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2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate

In the 3-hy­droxy­picolinate anion of the title salt, C(6)H(9)N(2) (+)·C(6)H(4)NO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar, with a dihedral angle of 9.55 (9)° between the pyridine ring and the carboxyl­ate group. I...

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Autores principales: Farhadikoutenaei, Abbas, Thanigaimani, Kaliyaperumal, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770389/
https://www.ncbi.nlm.nih.gov/pubmed/24046674
http://dx.doi.org/10.1107/S1600536813016322
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author Farhadikoutenaei, Abbas
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Farhadikoutenaei, Abbas
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Farhadikoutenaei, Abbas
collection PubMed
description In the 3-hy­droxy­picolinate anion of the title salt, C(6)H(9)N(2) (+)·C(6)H(4)NO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar, with a dihedral angle of 9.55 (9)° between the pyridine ring and the carboxyl­ate group. In the crystal, the cations and anions are linked via N—H⋯O hydrogen bonds, forming a centrosymmetric 2 + 2 aggregate with R (2) (2)(8) and R (4) (2)(8) ring motifs. The crystal structure also features N—H⋯N and weak C—H⋯π inter­actions.
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spelling pubmed-37703892013-09-17 2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate Farhadikoutenaei, Abbas Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the 3-hy­droxy­picolinate anion of the title salt, C(6)H(9)N(2) (+)·C(6)H(4)NO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar, with a dihedral angle of 9.55 (9)° between the pyridine ring and the carboxyl­ate group. In the crystal, the cations and anions are linked via N—H⋯O hydrogen bonds, forming a centrosymmetric 2 + 2 aggregate with R (2) (2)(8) and R (4) (2)(8) ring motifs. The crystal structure also features N—H⋯N and weak C—H⋯π inter­actions. International Union of Crystallography 2013-06-19 /pmc/articles/PMC3770389/ /pubmed/24046674 http://dx.doi.org/10.1107/S1600536813016322 Text en © Farhadikoutenaei et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Farhadikoutenaei, Abbas
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
title 2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
title_full 2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
title_fullStr 2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
title_full_unstemmed 2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
title_short 2-Amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
title_sort 2-amino-5-methyl­pyridinium 3-hy­droxy­pyridine-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770389/
https://www.ncbi.nlm.nih.gov/pubmed/24046674
http://dx.doi.org/10.1107/S1600536813016322
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