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2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate

In the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the anion is essentially planar, with a dihedral angle of 2.72 (17)° between the benzene ring and the carboxyl­ate group. In the crystal, the anions are connected by O—H⋯O hydrogen bonds, forming a 4(1) helical chain along the c axis. The protona...

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Autores principales: Khalib, Nuridayanti Che, Thanigaimani, Kaliyaperumal, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770390/
https://www.ncbi.nlm.nih.gov/pubmed/24046675
http://dx.doi.org/10.1107/S1600536813016310
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author Khalib, Nuridayanti Che
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Khalib, Nuridayanti Che
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Khalib, Nuridayanti Che
collection PubMed
description In the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the anion is essentially planar, with a dihedral angle of 2.72 (17)° between the benzene ring and the carboxyl­ate group. In the crystal, the anions are connected by O—H⋯O hydrogen bonds, forming a 4(1) helical chain along the c axis. The protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif. The ion pairs are further connected via another N—H⋯O hydrogen bond, resulting in a three-dimensional network.
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spelling pubmed-37703902013-09-17 2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate Khalib, Nuridayanti Che Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the anion is essentially planar, with a dihedral angle of 2.72 (17)° between the benzene ring and the carboxyl­ate group. In the crystal, the anions are connected by O—H⋯O hydrogen bonds, forming a 4(1) helical chain along the c axis. The protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif. The ion pairs are further connected via another N—H⋯O hydrogen bond, resulting in a three-dimensional network. International Union of Crystallography 2013-06-19 /pmc/articles/PMC3770390/ /pubmed/24046675 http://dx.doi.org/10.1107/S1600536813016310 Text en © Khalib et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khalib, Nuridayanti Che
Thanigaimani, Kaliyaperumal
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate
title 2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate
title_full 2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate
title_fullStr 2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate
title_full_unstemmed 2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate
title_short 2-Amino-4-methyl­pyridinium 3-hy­droxy­benzoate
title_sort 2-amino-4-methyl­pyridinium 3-hy­droxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770390/
https://www.ncbi.nlm.nih.gov/pubmed/24046675
http://dx.doi.org/10.1107/S1600536813016310
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