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2-Amino-4-methylpyridinium 3-hydroxybenzoate
In the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the anion is essentially planar, with a dihedral angle of 2.72 (17)° between the benzene ring and the carboxylate group. In the crystal, the anions are connected by O—H⋯O hydrogen bonds, forming a 4(1) helical chain along the c axis. The protona...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770390/ https://www.ncbi.nlm.nih.gov/pubmed/24046675 http://dx.doi.org/10.1107/S1600536813016310 |
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author | Khalib, Nuridayanti Che Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul |
author_facet | Khalib, Nuridayanti Che Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul |
author_sort | Khalib, Nuridayanti Che |
collection | PubMed |
description | In the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the anion is essentially planar, with a dihedral angle of 2.72 (17)° between the benzene ring and the carboxylate group. In the crystal, the anions are connected by O—H⋯O hydrogen bonds, forming a 4(1) helical chain along the c axis. The protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif. The ion pairs are further connected via another N—H⋯O hydrogen bond, resulting in a three-dimensional network. |
format | Online Article Text |
id | pubmed-3770390 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37703902013-09-17 2-Amino-4-methylpyridinium 3-hydroxybenzoate Khalib, Nuridayanti Che Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the anion is essentially planar, with a dihedral angle of 2.72 (17)° between the benzene ring and the carboxylate group. In the crystal, the anions are connected by O—H⋯O hydrogen bonds, forming a 4(1) helical chain along the c axis. The protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif. The ion pairs are further connected via another N—H⋯O hydrogen bond, resulting in a three-dimensional network. International Union of Crystallography 2013-06-19 /pmc/articles/PMC3770390/ /pubmed/24046675 http://dx.doi.org/10.1107/S1600536813016310 Text en © Khalib et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Khalib, Nuridayanti Che Thanigaimani, Kaliyaperumal Arshad, Suhana Razak, Ibrahim Abdul 2-Amino-4-methylpyridinium 3-hydroxybenzoate |
title | 2-Amino-4-methylpyridinium 3-hydroxybenzoate |
title_full | 2-Amino-4-methylpyridinium 3-hydroxybenzoate |
title_fullStr | 2-Amino-4-methylpyridinium 3-hydroxybenzoate |
title_full_unstemmed | 2-Amino-4-methylpyridinium 3-hydroxybenzoate |
title_short | 2-Amino-4-methylpyridinium 3-hydroxybenzoate |
title_sort | 2-amino-4-methylpyridinium 3-hydroxybenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770390/ https://www.ncbi.nlm.nih.gov/pubmed/24046675 http://dx.doi.org/10.1107/S1600536813016310 |
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