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(E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate

In the title mol­ecule, C(18)H(13)BrO(2), the anthracene unit forms an angle of 46.91 (2)° with the mean plane of the methyl acrylate moiety. In the crystal, the mol­ecules arrange themselves into strands parallel to [010] and, due to the crystal symmetry, there are eight strands crossing the unit c...

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Detalles Bibliográficos
Autores principales: Bugenhagen, Bernhard, Al Jasem, Yosef, Hindawi, Bassam al, Al Rawashdeh, Nathir, Thiemann, Thies
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770404/
https://www.ncbi.nlm.nih.gov/pubmed/24046689
http://dx.doi.org/10.1107/S1600536813016905
Descripción
Sumario:In the title mol­ecule, C(18)H(13)BrO(2), the anthracene unit forms an angle of 46.91 (2)° with the mean plane of the methyl acrylate moiety. In the crystal, the mol­ecules arrange themselves into strands parallel to [010] and, due to the crystal symmetry, there are eight strands crossing the unit cell. In each strand, mol­ecules form short C—H⋯O and C—H⋯π contacts and have their anthracene groups parallel to each other. Neighboring strands, related by a c-glide operation, are connected via C—H⋯O inter­actions and form a layer parallel to (100). The arrangement of the acrylate and anthracene groups in the crystal do not allow for [2 + 2] or [4 + 4] cyclo­addition.