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(E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate

In the title mol­ecule, C(18)H(13)BrO(2), the anthracene unit forms an angle of 46.91 (2)° with the mean plane of the methyl acrylate moiety. In the crystal, the mol­ecules arrange themselves into strands parallel to [010] and, due to the crystal symmetry, there are eight strands crossing the unit c...

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Autores principales: Bugenhagen, Bernhard, Al Jasem, Yosef, Hindawi, Bassam al, Al Rawashdeh, Nathir, Thiemann, Thies
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770404/
https://www.ncbi.nlm.nih.gov/pubmed/24046689
http://dx.doi.org/10.1107/S1600536813016905
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author Bugenhagen, Bernhard
Al Jasem, Yosef
Hindawi, Bassam al
Al Rawashdeh, Nathir
Thiemann, Thies
author_facet Bugenhagen, Bernhard
Al Jasem, Yosef
Hindawi, Bassam al
Al Rawashdeh, Nathir
Thiemann, Thies
author_sort Bugenhagen, Bernhard
collection PubMed
description In the title mol­ecule, C(18)H(13)BrO(2), the anthracene unit forms an angle of 46.91 (2)° with the mean plane of the methyl acrylate moiety. In the crystal, the mol­ecules arrange themselves into strands parallel to [010] and, due to the crystal symmetry, there are eight strands crossing the unit cell. In each strand, mol­ecules form short C—H⋯O and C—H⋯π contacts and have their anthracene groups parallel to each other. Neighboring strands, related by a c-glide operation, are connected via C—H⋯O inter­actions and form a layer parallel to (100). The arrangement of the acrylate and anthracene groups in the crystal do not allow for [2 + 2] or [4 + 4] cyclo­addition.
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spelling pubmed-37704042013-09-17 (E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate Bugenhagen, Bernhard Al Jasem, Yosef Hindawi, Bassam al Al Rawashdeh, Nathir Thiemann, Thies Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(18)H(13)BrO(2), the anthracene unit forms an angle of 46.91 (2)° with the mean plane of the methyl acrylate moiety. In the crystal, the mol­ecules arrange themselves into strands parallel to [010] and, due to the crystal symmetry, there are eight strands crossing the unit cell. In each strand, mol­ecules form short C—H⋯O and C—H⋯π contacts and have their anthracene groups parallel to each other. Neighboring strands, related by a c-glide operation, are connected via C—H⋯O inter­actions and form a layer parallel to (100). The arrangement of the acrylate and anthracene groups in the crystal do not allow for [2 + 2] or [4 + 4] cyclo­addition. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3770404/ /pubmed/24046689 http://dx.doi.org/10.1107/S1600536813016905 Text en © Bugenhagen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bugenhagen, Bernhard
Al Jasem, Yosef
Hindawi, Bassam al
Al Rawashdeh, Nathir
Thiemann, Thies
(E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate
title (E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate
title_full (E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate
title_fullStr (E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate
title_full_unstemmed (E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate
title_short (E)-Methyl 3-(10-bromo­anthracen-9-yl)acrylate
title_sort (e)-methyl 3-(10-bromo­anthracen-9-yl)acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770404/
https://www.ncbi.nlm.nih.gov/pubmed/24046689
http://dx.doi.org/10.1107/S1600536813016905
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