3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride

In the title salt, C(13)H(14)NO(+)·Cl(−), the dihedral angle between the fused ring system (r.m.s. deviation = 0.039 Å) and the attached aldehyde group is 75.27 (16)°. In the crystal, the cation and anion are linked by an N—H⋯Cl hydrogen bond and the resulting pairs are connected into four-ion aggre...

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Autores principales: Prasath, R., Bhavana, P., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770407/
https://www.ncbi.nlm.nih.gov/pubmed/24046692
http://dx.doi.org/10.1107/S160053681301684X
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author Prasath, R.
Bhavana, P.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Prasath, R.
Bhavana, P.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Prasath, R.
collection PubMed
description In the title salt, C(13)H(14)NO(+)·Cl(−), the dihedral angle between the fused ring system (r.m.s. deviation = 0.039 Å) and the attached aldehyde group is 75.27 (16)°. In the crystal, the cation and anion are linked by an N—H⋯Cl hydrogen bond and the resulting pairs are connected into four-ion aggregates by π–π inter­actions between the C(6) and pyridinium rings [3.6450 (9) Å] of inversion-related quinolinium residues.
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spelling pubmed-37704072013-09-17 3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride Prasath, R. Bhavana, P. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(13)H(14)NO(+)·Cl(−), the dihedral angle between the fused ring system (r.m.s. deviation = 0.039 Å) and the attached aldehyde group is 75.27 (16)°. In the crystal, the cation and anion are linked by an N—H⋯Cl hydrogen bond and the resulting pairs are connected into four-ion aggregates by π–π inter­actions between the C(6) and pyridinium rings [3.6450 (9) Å] of inversion-related quinolinium residues. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3770407/ /pubmed/24046692 http://dx.doi.org/10.1107/S160053681301684X Text en © Prasath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prasath, R.
Bhavana, P.
Ng, Seik Weng
Tiekink, Edward R. T.
3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride
title 3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride
title_full 3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride
title_fullStr 3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride
title_full_unstemmed 3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride
title_short 3-Acetyl-2,4-di­methyl­quinolin-1-ium chloride
title_sort 3-acetyl-2,4-di­methyl­quinolin-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770407/
https://www.ncbi.nlm.nih.gov/pubmed/24046692
http://dx.doi.org/10.1107/S160053681301684X
work_keys_str_mv AT prasathr 3acetyl24dimethylquinolin1iumchloride
AT bhavanap 3acetyl24dimethylquinolin1iumchloride
AT ngseikweng 3acetyl24dimethylquinolin1iumchloride
AT tiekinkedwardrt 3acetyl24dimethylquinolin1iumchloride

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