Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate

In the title compound, 2C(12)H(20)N(2) (2+)·2H(3)O(+)·P(6)O(18) (6−)·2H(2)O, a protonated water mol­ecule bridges the centrosymmetrical anionic P(6)O(18) ring via O—H⋯O hydrogen bonds. The centrosymmetric hydrogen-bonded rings formed by four oxonium cations and four phosphate anions can be described...

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Autores principales: Ameur, Iness, Abid, Sonia, Al-Deyab, Salem S, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770409/
https://www.ncbi.nlm.nih.gov/pubmed/24046694
http://dx.doi.org/10.1107/S1600536813016759
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author Ameur, Iness
Abid, Sonia
Al-Deyab, Salem S
Rzaigui, Mohamed
author_facet Ameur, Iness
Abid, Sonia
Al-Deyab, Salem S
Rzaigui, Mohamed
author_sort Ameur, Iness
collection PubMed
description In the title compound, 2C(12)H(20)N(2) (2+)·2H(3)O(+)·P(6)O(18) (6−)·2H(2)O, a protonated water mol­ecule bridges the centrosymmetrical anionic P(6)O(18) ring via O—H⋯O hydrogen bonds. The centrosymmetric hydrogen-bonded rings formed by four oxonium cations and four phosphate anions can be described by an R (4) (8)(36) graph-set motif. The ring motifs are connected by hydrogen bonds into inorganic layers perpendicular to [100]. The 1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium cations are located between the layers, compensating their negative charge and establishing N—H⋯O hydrogen bonds with the O atoms of the anionic framework.
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spelling pubmed-37704092013-09-17 Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate Ameur, Iness Abid, Sonia Al-Deyab, Salem S Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(12)H(20)N(2) (2+)·2H(3)O(+)·P(6)O(18) (6−)·2H(2)O, a protonated water mol­ecule bridges the centrosymmetrical anionic P(6)O(18) ring via O—H⋯O hydrogen bonds. The centrosymmetric hydrogen-bonded rings formed by four oxonium cations and four phosphate anions can be described by an R (4) (8)(36) graph-set motif. The ring motifs are connected by hydrogen bonds into inorganic layers perpendicular to [100]. The 1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium cations are located between the layers, compensating their negative charge and establishing N—H⋯O hydrogen bonds with the O atoms of the anionic framework. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3770409/ /pubmed/24046694 http://dx.doi.org/10.1107/S1600536813016759 Text en © Ameur et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ameur, Iness
Abid, Sonia
Al-Deyab, Salem S
Rzaigui, Mohamed
Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
title Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
title_full Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
title_fullStr Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
title_full_unstemmed Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
title_short Bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
title_sort bis[1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium] bis­(oxonium) cyclo­hexa­phosphate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770409/
https://www.ncbi.nlm.nih.gov/pubmed/24046694
http://dx.doi.org/10.1107/S1600536813016759
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