1,6-Di­bromo­naphthalen-2-ol methanol monosolvate

The naphthol-containing mol­ecule of the title compound, C(10)H(6)Br(2)O·CH(3)OH, crystallized as a methanol monosolvate and is planar to within 0.069 (1) Å for all non-H atoms. In the crystal, mol­ecules are linked by two pairs of O—H⋯O hydrogen bonds, involving the methanol mol­ecule, forming dime...

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Detalles Bibliográficos
Autores principales: Sanders, Marisa B., Furkan, Tania, Leonard, Emily, Chan, Benny C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770412/
https://www.ncbi.nlm.nih.gov/pubmed/24046697
http://dx.doi.org/10.1107/S1600536813016371
Descripción
Sumario:The naphthol-containing mol­ecule of the title compound, C(10)H(6)Br(2)O·CH(3)OH, crystallized as a methanol monosolvate and is planar to within 0.069 (1) Å for all non-H atoms. In the crystal, mol­ecules are linked by two pairs of O—H⋯O hydrogen bonds, involving the methanol mol­ecule, forming dimer-like arrangements. The crystal structure is further stabilized by π–π stacking [centroid–centroid distance = 3.676 (2) Å] and Br⋯Br inter­actions [3.480 (4) and 3.786 (1) Å], forming a three-dimensional structure.

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