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N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate
In the title compound, C(10)H(4)N(2)O(6)·2H(2)O, the organic molecule has crystallographically imposed inversion symmetry. The atoms of the three fused rings of the molecule are coplanar within 0.0246 (8) Å, while the two hydroxy O atoms are displaced from the mean plane of the molecule by 0.127...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770415/ https://www.ncbi.nlm.nih.gov/pubmed/24046700 http://dx.doi.org/10.1107/S1600536813016991 |
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author | Centore, Roberto Carella, Antonio |
author_facet | Centore, Roberto Carella, Antonio |
author_sort | Centore, Roberto |
collection | PubMed |
description | In the title compound, C(10)H(4)N(2)O(6)·2H(2)O, the organic molecule has crystallographically imposed inversion symmetry. The atoms of the three fused rings of the molecule are coplanar within 0.0246 (8) Å, while the two hydroxy O atoms are displaced from the mean plane of the molecule by 0.127 (1) Å. In the crystal, infinite near-planar layers of close-packed molecules are formed by hydrogen bonding between water O—H donor groups and carbonyl O-atom acceptors, and by weak interactions between C—H donor groups and water O-atom acceptors. The layers are parallel to the {102} family of planes. The stacked planes are held together by hydrogen bonding between N—OH donor groups and water O-atom acceptors. |
format | Online Article Text |
id | pubmed-3770415 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37704152013-09-17 N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate Centore, Roberto Carella, Antonio Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(4)N(2)O(6)·2H(2)O, the organic molecule has crystallographically imposed inversion symmetry. The atoms of the three fused rings of the molecule are coplanar within 0.0246 (8) Å, while the two hydroxy O atoms are displaced from the mean plane of the molecule by 0.127 (1) Å. In the crystal, infinite near-planar layers of close-packed molecules are formed by hydrogen bonding between water O—H donor groups and carbonyl O-atom acceptors, and by weak interactions between C—H donor groups and water O-atom acceptors. The layers are parallel to the {102} family of planes. The stacked planes are held together by hydrogen bonding between N—OH donor groups and water O-atom acceptors. International Union of Crystallography 2013-06-26 /pmc/articles/PMC3770415/ /pubmed/24046700 http://dx.doi.org/10.1107/S1600536813016991 Text en © Centore and Carella 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Centore, Roberto Carella, Antonio N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
title |
N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
title_full |
N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
title_fullStr |
N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
title_full_unstemmed |
N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
title_short |
N,N′-Dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
title_sort | n,n′-dihydroxybenzene-1,2:4,5-tetracarboximide dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770415/ https://www.ncbi.nlm.nih.gov/pubmed/24046700 http://dx.doi.org/10.1107/S1600536813016991 |
work_keys_str_mv | AT centoreroberto nndihydroxybenzene1245tetracarboximidedihydrate AT carellaantonio nndihydroxybenzene1245tetracarboximidedihydrate |