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N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate

In the title compound, C(10)H(4)N(2)O(6)·2H(2)O, the organic mol­ecule has crystallographically imposed inversion symmetry. The atoms of the three fused rings of the mol­ecule are coplanar within 0.0246 (8) Å, while the two hy­droxy O atoms are displaced from the mean plane of the mol­ecule by 0.127...

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Detalles Bibliográficos
Autores principales: Centore, Roberto, Carella, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770415/
https://www.ncbi.nlm.nih.gov/pubmed/24046700
http://dx.doi.org/10.1107/S1600536813016991
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author Centore, Roberto
Carella, Antonio
author_facet Centore, Roberto
Carella, Antonio
author_sort Centore, Roberto
collection PubMed
description In the title compound, C(10)H(4)N(2)O(6)·2H(2)O, the organic mol­ecule has crystallographically imposed inversion symmetry. The atoms of the three fused rings of the mol­ecule are coplanar within 0.0246 (8) Å, while the two hy­droxy O atoms are displaced from the mean plane of the mol­ecule by 0.127 (1) Å. In the crystal, infinite near-planar layers of close-packed mol­ecules are formed by hydrogen bonding between water O—H donor groups and carbonyl O-atom acceptors, and by weak inter­actions between C—H donor groups and water O-atom acceptors. The layers are parallel to the {102} family of planes. The stacked planes are held together by hydrogen bonding between N—OH donor groups and water O-atom acceptors.
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spelling pubmed-37704152013-09-17 N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate Centore, Roberto Carella, Antonio Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(4)N(2)O(6)·2H(2)O, the organic mol­ecule has crystallographically imposed inversion symmetry. The atoms of the three fused rings of the mol­ecule are coplanar within 0.0246 (8) Å, while the two hy­droxy O atoms are displaced from the mean plane of the mol­ecule by 0.127 (1) Å. In the crystal, infinite near-planar layers of close-packed mol­ecules are formed by hydrogen bonding between water O—H donor groups and carbonyl O-atom acceptors, and by weak inter­actions between C—H donor groups and water O-atom acceptors. The layers are parallel to the {102} family of planes. The stacked planes are held together by hydrogen bonding between N—OH donor groups and water O-atom acceptors. International Union of Crystallography 2013-06-26 /pmc/articles/PMC3770415/ /pubmed/24046700 http://dx.doi.org/10.1107/S1600536813016991 Text en © Centore and Carella 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Centore, Roberto
Carella, Antonio
N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
title N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
title_full N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
title_fullStr N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
title_full_unstemmed N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
title_short N,N′-Di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
title_sort n,n′-di­hydroxy­benzene-1,2:4,5-tetra­carboximide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770415/
https://www.ncbi.nlm.nih.gov/pubmed/24046700
http://dx.doi.org/10.1107/S1600536813016991
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