2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde

The structure of the title compound, C(7)H(4)OS(4), at 100 K has ortho­rhom­bic symmetry. In the crystal, tetra­thia­fulvalene mol­ecules form π-stacks along the a axis, with a stacking distance of 3.4736 (6) Å. Along the b axis, parallel stacks are inter­connected with each other through a network...

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Detalles Bibliográficos
Autores principales: Zeller, Matthias, Azov, Vladimir A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770418/
https://www.ncbi.nlm.nih.gov/pubmed/24046703
http://dx.doi.org/10.1107/S160053681301711X
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author Zeller, Matthias
Azov, Vladimir A.
author_facet Zeller, Matthias
Azov, Vladimir A.
author_sort Zeller, Matthias
collection PubMed
description The structure of the title compound, C(7)H(4)OS(4), at 100 K has ortho­rhom­bic symmetry. In the crystal, tetra­thia­fulvalene mol­ecules form π-stacks along the a axis, with a stacking distance of 3.4736 (6) Å. Along the b axis, parallel stacks are inter­connected with each other through a network of weak C—H⋯O hydrogen bonds and short S⋯S contacts [3.4813 (7) Å]. Additional short S⋯S contacts [3.4980 (9) Å] join parallel stacks along the c axis.
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spelling pubmed-37704182013-09-17 2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde Zeller, Matthias Azov, Vladimir A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(7)H(4)OS(4), at 100 K has ortho­rhom­bic symmetry. In the crystal, tetra­thia­fulvalene mol­ecules form π-stacks along the a axis, with a stacking distance of 3.4736 (6) Å. Along the b axis, parallel stacks are inter­connected with each other through a network of weak C—H⋯O hydrogen bonds and short S⋯S contacts [3.4813 (7) Å]. Additional short S⋯S contacts [3.4980 (9) Å] join parallel stacks along the c axis. International Union of Crystallography 2013-06-26 /pmc/articles/PMC3770418/ /pubmed/24046703 http://dx.doi.org/10.1107/S160053681301711X Text en © Zeller and Azov 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zeller, Matthias
Azov, Vladimir A.
2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
title 2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
title_full 2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
title_fullStr 2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
title_full_unstemmed 2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
title_short 2-(1,3-Di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
title_sort 2-(1,3-di­thiol-2-yl­idene)-1,3-di­thiole-4-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770418/
https://www.ncbi.nlm.nih.gov/pubmed/24046703
http://dx.doi.org/10.1107/S160053681301711X
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