N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate

The title compound, C(21)H(17)N(3)O(5)·C(3)H(7)NO, exists in an E conformation with respect to the azomethine double bond of the hydrazide mol­ecule. This mol­ecule contains an intra­molecular O—H⋯N hydrogen bond, while an inter­molecular N—H⋯O hydrogen bond links the hydrazide to the formamide mol­...

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Detalles Bibliográficos
Autores principales: Joseph, Bibitha, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770421/
https://www.ncbi.nlm.nih.gov/pubmed/24046706
http://dx.doi.org/10.1107/S1600536813017091
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author Joseph, Bibitha
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Joseph, Bibitha
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Joseph, Bibitha
collection PubMed
description The title compound, C(21)H(17)N(3)O(5)·C(3)H(7)NO, exists in an E conformation with respect to the azomethine double bond of the hydrazide mol­ecule. This mol­ecule contains an intra­molecular O—H⋯N hydrogen bond, while an inter­molecular N—H⋯O hydrogen bond links the hydrazide to the formamide mol­ecule of solvation. Nonclassical C—H⋯O inter­molecular hydrogen bonds build up a supra­molecular architecture, together with two C—H⋯π inter­actions and a weak π–π inter­action, with a centroid–centroid distance of 3.650 (13) Å.
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spelling pubmed-37704212013-09-17 N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate Joseph, Bibitha Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(17)N(3)O(5)·C(3)H(7)NO, exists in an E conformation with respect to the azomethine double bond of the hydrazide mol­ecule. This mol­ecule contains an intra­molecular O—H⋯N hydrogen bond, while an inter­molecular N—H⋯O hydrogen bond links the hydrazide to the formamide mol­ecule of solvation. Nonclassical C—H⋯O inter­molecular hydrogen bonds build up a supra­molecular architecture, together with two C—H⋯π inter­actions and a weak π–π inter­action, with a centroid–centroid distance of 3.650 (13) Å. International Union of Crystallography 2013-06-26 /pmc/articles/PMC3770421/ /pubmed/24046706 http://dx.doi.org/10.1107/S1600536813017091 Text en © Joseph et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Joseph, Bibitha
Sithambaresan, M.
Kurup, M. R. Prathapachandra
N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
title N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
title_full N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
title_fullStr N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
title_full_unstemmed N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
title_short N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
title_sort n′-[(e)-4-benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770421/
https://www.ncbi.nlm.nih.gov/pubmed/24046706
http://dx.doi.org/10.1107/S1600536813017091
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AT kurupmrprathapachandra ne4benzyloxy2hydroxybenzylidene4nitrobenzohydrazidedimethylformamidemonosolvate

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