rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate

In the racemic title compound, C(14)H(16)BrNO(3)S(2), synthesized from the corresponding ω-bromo­propio­phenone, the dihedral angle between the plane of the phenol group and that of the planar section [maximum deviation = 0.040 (2) Å] of the morpholine-4-carbodi­thiol­ate moiety is 76.36 (10)°. A st...

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Detalles Bibliográficos
Autores principales: Sarbu, Laura G., Hrib, Cristian G., Birsa, Lucian M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770428/
https://www.ncbi.nlm.nih.gov/pubmed/24046713
http://dx.doi.org/10.1107/S1600536813017509
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author Sarbu, Laura G.
Hrib, Cristian G.
Birsa, Lucian M.
author_facet Sarbu, Laura G.
Hrib, Cristian G.
Birsa, Lucian M.
author_sort Sarbu, Laura G.
collection PubMed
description In the racemic title compound, C(14)H(16)BrNO(3)S(2), synthesized from the corresponding ω-bromo­propio­phenone, the dihedral angle between the plane of the phenol group and that of the planar section [maximum deviation = 0.040 (2) Å] of the morpholine-4-carbodi­thiol­ate moiety is 76.36 (10)°. A strong intra­molecular phenol O—H⋯O hydrogen bond if present in the mol­ecule. In the crystal, only weak C—H⋯S and C—H⋯O inter­actions are found.
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spelling pubmed-37704282013-09-17 rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate Sarbu, Laura G. Hrib, Cristian G. Birsa, Lucian M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the racemic title compound, C(14)H(16)BrNO(3)S(2), synthesized from the corresponding ω-bromo­propio­phenone, the dihedral angle between the plane of the phenol group and that of the planar section [maximum deviation = 0.040 (2) Å] of the morpholine-4-carbodi­thiol­ate moiety is 76.36 (10)°. A strong intra­molecular phenol O—H⋯O hydrogen bond if present in the mol­ecule. In the crystal, only weak C—H⋯S and C—H⋯O inter­actions are found. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3770428/ /pubmed/24046713 http://dx.doi.org/10.1107/S1600536813017509 Text en © Sarbu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sarbu, Laura G.
Hrib, Cristian G.
Birsa, Lucian M.
rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
title rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
title_full rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
title_fullStr rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
title_full_unstemmed rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
title_short rac-1-(5-Bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
title_sort rac-1-(5-bromo-2-hy­droxy­phen­yl)-1-oxopropan-2-yl morpholine-4-carbo­dithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770428/
https://www.ncbi.nlm.nih.gov/pubmed/24046713
http://dx.doi.org/10.1107/S1600536813017509
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