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(E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate
In the title compound, C(14)H(13)N(3)O(2)·2H(2)O, the hydrazone molecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methylidene–hydrazide [–C(=O)–N–N=C–] fragment is essentially planar, with a maximum deviatio...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770434/ https://www.ncbi.nlm.nih.gov/pubmed/24046719 http://dx.doi.org/10.1107/S1600536813017406 |
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author | Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali |
author_facet | Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali |
author_sort | Novina, J. Josephine |
collection | PubMed |
description | In the title compound, C(14)H(13)N(3)O(2)·2H(2)O, the hydrazone molecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methylidene–hydrazide [–C(=O)–N–N=C–] fragment is essentially planar, with a maximum deviation of 0.0375 (13) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 2.71 (14) and 11.25 (13)°, respectively, with mean plane of the methylidene-hydrazide fragment. In the crystal, the benzohydrazide and water molecules are linked by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3770434 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37704342013-09-17 (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)N(3)O(2)·2H(2)O, the hydrazone molecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methylidene–hydrazide [–C(=O)–N–N=C–] fragment is essentially planar, with a maximum deviation of 0.0375 (13) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 2.71 (14) and 11.25 (13)°, respectively, with mean plane of the methylidene-hydrazide fragment. In the crystal, the benzohydrazide and water molecules are linked by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3770434/ /pubmed/24046719 http://dx.doi.org/10.1107/S1600536813017406 Text en © Novina et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
title | (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
title_full | (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
title_fullStr | (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
title_full_unstemmed | (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
title_short | (E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
title_sort | (e)-n′-(4-methoxybenzylidene)pyridine-3-carbohydrazide dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770434/ https://www.ncbi.nlm.nih.gov/pubmed/24046719 http://dx.doi.org/10.1107/S1600536813017406 |
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