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(E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate

In the title compound, C(14)H(13)N(3)O(2)·2H(2)O, the hydrazone mol­ecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methyl­idene–hydrazide [–C(=O)–N–N=C–] fragment is essentially planar, with a maximum deviatio...

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Autores principales: Novina, J. Josephine, Vasuki, G., Suresh, M., Padusha, M. Syed Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770434/
https://www.ncbi.nlm.nih.gov/pubmed/24046719
http://dx.doi.org/10.1107/S1600536813017406
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author Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
author_facet Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
author_sort Novina, J. Josephine
collection PubMed
description In the title compound, C(14)H(13)N(3)O(2)·2H(2)O, the hydrazone mol­ecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methyl­idene–hydrazide [–C(=O)–N–N=C–] fragment is essentially planar, with a maximum deviation of 0.0375 (13) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 2.71 (14) and 11.25 (13)°, respectively, with mean plane of the methyl­idene-hydrazide fragment. In the crystal, the benzohydrazide and water mol­ecules are linked by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network.
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spelling pubmed-37704342013-09-17 (E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)N(3)O(2)·2H(2)O, the hydrazone mol­ecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methyl­idene–hydrazide [–C(=O)–N–N=C–] fragment is essentially planar, with a maximum deviation of 0.0375 (13) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 2.71 (14) and 11.25 (13)°, respectively, with mean plane of the methyl­idene-hydrazide fragment. In the crystal, the benzohydrazide and water mol­ecules are linked by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3770434/ /pubmed/24046719 http://dx.doi.org/10.1107/S1600536813017406 Text en © Novina et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
(E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
title (E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
title_full (E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
title_fullStr (E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
title_full_unstemmed (E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
title_short (E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
title_sort (e)-n′-(4-meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770434/
https://www.ncbi.nlm.nih.gov/pubmed/24046719
http://dx.doi.org/10.1107/S1600536813017406
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