1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine

In the title compound, C(18)H(20)F(2)N(2)O(2)S, the central piperazine ring adopts a chair conformation. The dihedral angle between the two benzene rings is 40.20°, whereas those between the piperazine ring (considering the best fit plane through all the non-H atoms) and the sulfonyl-bound benzene a...

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Detalles Bibliográficos
Autores principales: Sreenivasa, S., Anitha, H. C., Suchetan, P. A., Palakshamurthy, B. S., Savanur, J., Tonannavar, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770435/
https://www.ncbi.nlm.nih.gov/pubmed/24046720
http://dx.doi.org/10.1107/S1600536813016462
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author Sreenivasa, S.
Anitha, H. C.
Suchetan, P. A.
Palakshamurthy, B. S.
Savanur, J.
Tonannavar, J.
author_facet Sreenivasa, S.
Anitha, H. C.
Suchetan, P. A.
Palakshamurthy, B. S.
Savanur, J.
Tonannavar, J.
author_sort Sreenivasa, S.
collection PubMed
description In the title compound, C(18)H(20)F(2)N(2)O(2)S, the central piperazine ring adopts a chair conformation. The dihedral angle between the two benzene rings is 40.20°, whereas those between the piperazine ring (considering the best fit plane through all the non-H atoms) and the sulfonyl-bound benzene and di­fluoro­benzene rings are 74.96 and 86.16°, respectively. In the crystal, mol­ecules are stacked along the a axis through weak C—H⋯O and C—H⋯F inter­actions.
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spelling pubmed-37704352013-09-17 1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine Sreenivasa, S. Anitha, H. C. Suchetan, P. A. Palakshamurthy, B. S. Savanur, J. Tonannavar, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(20)F(2)N(2)O(2)S, the central piperazine ring adopts a chair conformation. The dihedral angle between the two benzene rings is 40.20°, whereas those between the piperazine ring (considering the best fit plane through all the non-H atoms) and the sulfonyl-bound benzene and di­fluoro­benzene rings are 74.96 and 86.16°, respectively. In the crystal, mol­ecules are stacked along the a axis through weak C—H⋯O and C—H⋯F inter­actions. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3770435/ /pubmed/24046720 http://dx.doi.org/10.1107/S1600536813016462 Text en © Sreenivasa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sreenivasa, S.
Anitha, H. C.
Suchetan, P. A.
Palakshamurthy, B. S.
Savanur, J.
Tonannavar, J.
1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
title 1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
title_full 1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
title_fullStr 1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
title_full_unstemmed 1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
title_short 1-(3,4-Di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
title_sort 1-(3,4-di­fluoro­benz­yl)-4-(4-methyl­phenyl­sulfon­yl)piperazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770435/
https://www.ncbi.nlm.nih.gov/pubmed/24046720
http://dx.doi.org/10.1107/S1600536813016462
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