3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide

In the title compound, C(17)H(25)N(3)O(2)S, the terminal and central amide groups are, respectively, twisted and coplanar with the attached benzene ring [O—C—C—C torsion angles = 22.7 (3) and 5.4 (3)°]. In the central part of the mol­ecule, the amide and thio­amide residues are approximately perpend...

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Detalles Bibliográficos
Autores principales: Selvakumaran, N., Karvembu, R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770438/
https://www.ncbi.nlm.nih.gov/pubmed/24046723
http://dx.doi.org/10.1107/S1600536813017455
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author Selvakumaran, N.
Karvembu, R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Selvakumaran, N.
Karvembu, R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Selvakumaran, N.
collection PubMed
description In the title compound, C(17)H(25)N(3)O(2)S, the terminal and central amide groups are, respectively, twisted and coplanar with the attached benzene ring [O—C—C—C torsion angles = 22.7 (3) and 5.4 (3)°]. In the central part of the mol­ecule, the amide and thio­amide residues are approximately perpendicular [C—N—C—S torsion angle = −104.98 (18)°]. Supra­molecular layers with a zigzag topology are formed in the crystal packing by N—H⋯O, N—H⋯S and C—H⋯O inter­actions; these stack along c, being separated by hydro­phobic inter­actions.
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spelling pubmed-37704382013-09-17 3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide Selvakumaran, N. Karvembu, R. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(25)N(3)O(2)S, the terminal and central amide groups are, respectively, twisted and coplanar with the attached benzene ring [O—C—C—C torsion angles = 22.7 (3) and 5.4 (3)°]. In the central part of the mol­ecule, the amide and thio­amide residues are approximately perpendicular [C—N—C—S torsion angle = −104.98 (18)°]. Supra­molecular layers with a zigzag topology are formed in the crystal packing by N—H⋯O, N—H⋯S and C—H⋯O inter­actions; these stack along c, being separated by hydro­phobic inter­actions. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3770438/ /pubmed/24046723 http://dx.doi.org/10.1107/S1600536813017455 Text en © Selvakumaran et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvakumaran, N.
Karvembu, R.
Ng, Seik Weng
Tiekink, Edward R. T.
3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
title 3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
title_full 3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
title_fullStr 3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
title_full_unstemmed 3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
title_short 3-({[Bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
title_sort 3-({[bis(2-methyl­prop­yl)carbamo­thio­yl]amino}­carbon­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3770438/
https://www.ncbi.nlm.nih.gov/pubmed/24046723
http://dx.doi.org/10.1107/S1600536813017455
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AT karvembur 3bis2methylpropylcarbamothioylaminocarbonylbenzamide
AT ngseikweng 3bis2methylpropylcarbamothioylaminocarbonylbenzamide
AT tiekinkedwardrt 3bis2methylpropylcarbamothioylaminocarbonylbenzamide

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