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Bis(3-chlorobenzoato-κ(2) O,O′)bis(nicotinamide-κN)copper(II)
The molecule of the title Cu(II) complex, [Cu(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)], contains two 3-chlorobenzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN(2)O(4) coordination polyhedron is a considerably disto...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772403/ https://www.ncbi.nlm.nih.gov/pubmed/24046546 http://dx.doi.org/10.1107/S1600536813014694 |
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author | Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Bozkurt, Nihat |
collection | PubMed |
description | The molecule of the title Cu(II) complex, [Cu(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)], contains two 3-chlorobenzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN(2)O(4) coordination polyhedron is a considerably distorted octahedron. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 17.92 (12) and 24.69 (16)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 52.20 (8) and 1.56 (6)°. In the crystal, N—H⋯N and C—H⋯O hydrogen bonds link the molecules into a three–dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.982 (2) Å] may further stabilize the crystal structure. |
format | Online Article Text |
id | pubmed-3772403 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724032013-09-17 Bis(3-chlorobenzoato-κ(2) O,O′)bis(nicotinamide-κN)copper(II) Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title Cu(II) complex, [Cu(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)], contains two 3-chlorobenzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN(2)O(4) coordination polyhedron is a considerably distorted octahedron. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 17.92 (12) and 24.69 (16)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 52.20 (8) and 1.56 (6)°. In the crystal, N—H⋯N and C—H⋯O hydrogen bonds link the molecules into a three–dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.982 (2) Å] may further stabilize the crystal structure. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772403/ /pubmed/24046546 http://dx.doi.org/10.1107/S1600536813014694 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Bis(3-chlorobenzoato-κ(2) O,O′)bis(nicotinamide-κN)copper(II) |
title | Bis(3-chlorobenzoato-κ(2)
O,O′)bis(nicotinamide-κN)copper(II) |
title_full | Bis(3-chlorobenzoato-κ(2)
O,O′)bis(nicotinamide-κN)copper(II) |
title_fullStr | Bis(3-chlorobenzoato-κ(2)
O,O′)bis(nicotinamide-κN)copper(II) |
title_full_unstemmed | Bis(3-chlorobenzoato-κ(2)
O,O′)bis(nicotinamide-κN)copper(II) |
title_short | Bis(3-chlorobenzoato-κ(2)
O,O′)bis(nicotinamide-κN)copper(II) |
title_sort | bis(3-chlorobenzoato-κ(2)
o,o′)bis(nicotinamide-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772403/ https://www.ncbi.nlm.nih.gov/pubmed/24046546 http://dx.doi.org/10.1107/S1600536813014694 |
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