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Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)

The mol­ecule of the title Cu(II) complex, [Cu(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)], contains two 3-chloro­benzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN(2)O(4) coordination polyhedron is a considerably disto...

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Autores principales: Bozkurt, Nihat, Dilek, Nefise, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772403/
https://www.ncbi.nlm.nih.gov/pubmed/24046546
http://dx.doi.org/10.1107/S1600536813014694
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author Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Bozkurt, Nihat
collection PubMed
description The mol­ecule of the title Cu(II) complex, [Cu(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)], contains two 3-chloro­benzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN(2)O(4) coordination polyhedron is a considerably distorted octahedron. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 17.92 (12) and 24.69 (16)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 52.20 (8) and 1.56 (6)°. In the crystal, N—H⋯N and C—H⋯O hydrogen bonds link the mol­ecules into a three–dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.982 (2) Å] may further stabilize the crystal structure.
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spelling pubmed-37724032013-09-17 Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II) Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title Cu(II) complex, [Cu(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)], contains two 3-chloro­benzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN(2)O(4) coordination polyhedron is a considerably distorted octahedron. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 17.92 (12) and 24.69 (16)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 52.20 (8) and 1.56 (6)°. In the crystal, N—H⋯N and C—H⋯O hydrogen bonds link the mol­ecules into a three–dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.982 (2) Å] may further stabilize the crystal structure. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772403/ /pubmed/24046546 http://dx.doi.org/10.1107/S1600536813014694 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)
title Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)
title_full Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)
title_fullStr Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)
title_full_unstemmed Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)
title_short Bis(3-chloro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN)copper(II)
title_sort bis(3-chloro­benzoato-κ(2) o,o′)bis­(nicotinamide-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772403/
https://www.ncbi.nlm.nih.gov/pubmed/24046546
http://dx.doi.org/10.1107/S1600536813014694
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