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Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate]
In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water molecule and seven O atoms from four 5-(pyridine-4-carboxamido)isophthalate (L) ligands in a distorted square-antiprismatic arrangement, while the Ni(II) ion, lying on an inve...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772404/ https://www.ncbi.nlm.nih.gov/pubmed/24046547 http://dx.doi.org/10.1107/S1600536813014876 |
Sumario: | In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water molecule and seven O atoms from four 5-(pyridine-4-carboxamido)isophthalate (L) ligands in a distorted square-antiprismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octahedral geometry by two pyridine N atoms, two carboxylate O atoms and two water molecules. One L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxylate groups and one pyridine N atom. The other L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxylate groups, while the uncoordinating pyridine N atom is hydrogen bonded to an adjacent coordinating water molecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds play an important role in stabilizing the crystal structure. |
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