Cargando…
Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate]
In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water molecule and seven O atoms from four 5-(pyridine-4-carboxamido)isophthalate (L) ligands in a distorted square-antiprismatic arrangement, while the Ni(II) ion, lying on an inve...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772404/ https://www.ncbi.nlm.nih.gov/pubmed/24046547 http://dx.doi.org/10.1107/S1600536813014876 |
_version_ | 1782284320920043520 |
---|---|
author | Deng, Yi-Fang Chen, Man-Sheng Zhang, Chun-Hua Nie, Xue |
author_facet | Deng, Yi-Fang Chen, Man-Sheng Zhang, Chun-Hua Nie, Xue |
author_sort | Deng, Yi-Fang |
collection | PubMed |
description | In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water molecule and seven O atoms from four 5-(pyridine-4-carboxamido)isophthalate (L) ligands in a distorted square-antiprismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octahedral geometry by two pyridine N atoms, two carboxylate O atoms and two water molecules. One L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxylate groups and one pyridine N atom. The other L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxylate groups, while the uncoordinating pyridine N atom is hydrogen bonded to an adjacent coordinating water molecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds play an important role in stabilizing the crystal structure. |
format | Online Article Text |
id | pubmed-3772404 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724042013-09-17 Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] Deng, Yi-Fang Chen, Man-Sheng Zhang, Chun-Hua Nie, Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water molecule and seven O atoms from four 5-(pyridine-4-carboxamido)isophthalate (L) ligands in a distorted square-antiprismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octahedral geometry by two pyridine N atoms, two carboxylate O atoms and two water molecules. One L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxylate groups and one pyridine N atom. The other L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxylate groups, while the uncoordinating pyridine N atom is hydrogen bonded to an adjacent coordinating water molecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds play an important role in stabilizing the crystal structure. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772404/ /pubmed/24046547 http://dx.doi.org/10.1107/S1600536813014876 Text en © Deng et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Deng, Yi-Fang Chen, Man-Sheng Zhang, Chun-Hua Nie, Xue Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] |
title | Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] |
title_full | Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] |
title_fullStr | Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] |
title_full_unstemmed | Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] |
title_short | Poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate] |
title_sort | poly[[tetraaquatetrakis[μ(3)-5-(pyridine-4-carboxamido)isophthalato]nickel(ii)diterbium(iii)] tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772404/ https://www.ncbi.nlm.nih.gov/pubmed/24046547 http://dx.doi.org/10.1107/S1600536813014876 |
work_keys_str_mv | AT dengyifang polytetraaquatetrakism35pyridine4carboxamidoisophthalatonickeliiditerbiumiiitetrahydrate AT chenmansheng polytetraaquatetrakism35pyridine4carboxamidoisophthalatonickeliiditerbiumiiitetrahydrate AT zhangchunhua polytetraaquatetrakism35pyridine4carboxamidoisophthalatonickeliiditerbiumiiitetrahydrate AT niexue polytetraaquatetrakism35pyridine4carboxamidoisophthalatonickeliiditerbiumiiitetrahydrate |