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Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]

In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water mol­ecule and seven O atoms from four 5-(pyridine-4-carboxamido)­isophthalate (L) ligands in a distorted square-anti­prismatic arrangement, while the Ni(II) ion, lying on an inve...

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Autores principales: Deng, Yi-Fang, Chen, Man-Sheng, Zhang, Chun-Hua, Nie, Xue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772404/
https://www.ncbi.nlm.nih.gov/pubmed/24046547
http://dx.doi.org/10.1107/S1600536813014876
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author Deng, Yi-Fang
Chen, Man-Sheng
Zhang, Chun-Hua
Nie, Xue
author_facet Deng, Yi-Fang
Chen, Man-Sheng
Zhang, Chun-Hua
Nie, Xue
author_sort Deng, Yi-Fang
collection PubMed
description In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water mol­ecule and seven O atoms from four 5-(pyridine-4-carboxamido)­isophthalate (L) ligands in a distorted square-anti­prismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octa­hedral geometry by two pyridine N atoms, two carboxyl­ate O atoms and two water mol­ecules. One L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxyl­ate groups and one pyridine N atom. The other L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxyl­ate groups, while the uncoordinating pyridine N atom is hydrogen bonded to an adjacent coordinating water mol­ecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds play an important role in stabilizing the crystal structure.
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spelling pubmed-37724042013-09-17 Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate] Deng, Yi-Fang Chen, Man-Sheng Zhang, Chun-Hua Nie, Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[NiTb(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Tb(III) ion is coordinated by one water mol­ecule and seven O atoms from four 5-(pyridine-4-carboxamido)­isophthalate (L) ligands in a distorted square-anti­prismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octa­hedral geometry by two pyridine N atoms, two carboxyl­ate O atoms and two water mol­ecules. One L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxyl­ate groups and one pyridine N atom. The other L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxyl­ate groups, while the uncoordinating pyridine N atom is hydrogen bonded to an adjacent coordinating water mol­ecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds play an important role in stabilizing the crystal structure. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772404/ /pubmed/24046547 http://dx.doi.org/10.1107/S1600536813014876 Text en © Deng et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Yi-Fang
Chen, Man-Sheng
Zhang, Chun-Hua
Nie, Xue
Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]
title Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]
title_full Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]
title_fullStr Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]
title_full_unstemmed Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]
title_short Poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(II)diterbium(III)] tetra­hydrate]
title_sort poly[[tetra­aqua­tetra­kis­[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]nickel(ii)diterbium(iii)] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772404/
https://www.ncbi.nlm.nih.gov/pubmed/24046547
http://dx.doi.org/10.1107/S1600536813014876
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