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Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)

The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The mol­ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa­hedron, with two bidentate 2-pyridine­seleno­l...

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Detalles Bibliográficos
Autores principales: Mammadova, Gunay Z., Ismaylova, Sheyda R., Matsulevich, Zhanna V., Osmanov, Vladimir K., Borisov, Alexander V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772407/
https://www.ncbi.nlm.nih.gov/pubmed/24046550
http://dx.doi.org/10.1107/S1600536813014657
Descripción
Sumario:The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The mol­ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa­hedron, with two bidentate 2-pyridine­seleno­late ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π inter­actions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules into chains along the c axis.