Cargando…
Dichloridobis(pyridine-2-selenolato-κ(2) N,Se)tin(IV)
The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octahedron, with two bidentate 2-pyridineselenol...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772407/ https://www.ncbi.nlm.nih.gov/pubmed/24046550 http://dx.doi.org/10.1107/S1600536813014657 |
Sumario: | The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octahedron, with two bidentate 2-pyridineselenolate ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π interactions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak intermolecular C—H⋯Cl hydrogen bonds link the molecules into chains along the c axis. |
---|