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Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)

The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The mol­ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa­hedron, with two bidentate 2-pyridine­seleno­l...

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Autores principales: Mammadova, Gunay Z., Ismaylova, Sheyda R., Matsulevich, Zhanna V., Osmanov, Vladimir K., Borisov, Alexander V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772407/
https://www.ncbi.nlm.nih.gov/pubmed/24046550
http://dx.doi.org/10.1107/S1600536813014657
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author Mammadova, Gunay Z.
Ismaylova, Sheyda R.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
author_facet Mammadova, Gunay Z.
Ismaylova, Sheyda R.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
author_sort Mammadova, Gunay Z.
collection PubMed
description The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The mol­ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa­hedron, with two bidentate 2-pyridine­seleno­late ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π inter­actions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules into chains along the c axis.
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spelling pubmed-37724072013-09-17 Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV) Mammadova, Gunay Z. Ismaylova, Sheyda R. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The mol­ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa­hedron, with two bidentate 2-pyridine­seleno­late ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π inter­actions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules into chains along the c axis. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772407/ /pubmed/24046550 http://dx.doi.org/10.1107/S1600536813014657 Text en © Mammadova et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mammadova, Gunay Z.
Ismaylova, Sheyda R.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)
title Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)
title_full Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)
title_fullStr Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)
title_full_unstemmed Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)
title_short Dichloridobis(pyridine-2-seleno­lato-κ(2) N,Se)tin(IV)
title_sort dichloridobis(pyridine-2-seleno­lato-κ(2) n,se)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772407/
https://www.ncbi.nlm.nih.gov/pubmed/24046550
http://dx.doi.org/10.1107/S1600536813014657
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