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Dichloridobis(pyridine-2-selenolato-κ(2) N,Se)tin(IV)
The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octahedron, with two bidentate 2-pyridineselenol...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772407/ https://www.ncbi.nlm.nih.gov/pubmed/24046550 http://dx.doi.org/10.1107/S1600536813014657 |
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author | Mammadova, Gunay Z. Ismaylova, Sheyda R. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. |
author_facet | Mammadova, Gunay Z. Ismaylova, Sheyda R. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. |
author_sort | Mammadova, Gunay Z. |
collection | PubMed |
description | The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octahedron, with two bidentate 2-pyridineselenolate ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π interactions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak intermolecular C—H⋯Cl hydrogen bonds link the molecules into chains along the c axis. |
format | Online Article Text |
id | pubmed-3772407 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724072013-09-17 Dichloridobis(pyridine-2-selenolato-κ(2) N,Se)tin(IV) Mammadova, Gunay Z. Ismaylova, Sheyda R. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [SnCl(2)(C(5)H(4)NSe)(2)], is the product of a reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octahedron, with two bidentate 2-pyridineselenolate ligands inclined to each other at an angle of 83.96 (7)°. The two Sn—Cl and two Sn—N bonds are in cis configurations, while the two Sn—Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se—Sn—Se angle of 157.988 (15)°. In the crystal, π–π interactions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak intermolecular C—H⋯Cl hydrogen bonds link the molecules into chains along the c axis. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772407/ /pubmed/24046550 http://dx.doi.org/10.1107/S1600536813014657 Text en © Mammadova et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mammadova, Gunay Z. Ismaylova, Sheyda R. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. Dichloridobis(pyridine-2-selenolato-κ(2) N,Se)tin(IV) |
title | Dichloridobis(pyridine-2-selenolato-κ(2)
N,Se)tin(IV) |
title_full | Dichloridobis(pyridine-2-selenolato-κ(2)
N,Se)tin(IV) |
title_fullStr | Dichloridobis(pyridine-2-selenolato-κ(2)
N,Se)tin(IV) |
title_full_unstemmed | Dichloridobis(pyridine-2-selenolato-κ(2)
N,Se)tin(IV) |
title_short | Dichloridobis(pyridine-2-selenolato-κ(2)
N,Se)tin(IV) |
title_sort | dichloridobis(pyridine-2-selenolato-κ(2)
n,se)tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772407/ https://www.ncbi.nlm.nih.gov/pubmed/24046550 http://dx.doi.org/10.1107/S1600536813014657 |
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