Potassium N-bromo-4-chloro-2-methyl­benzene­sulfonamidate monohydrate

In the title compound, K(+)·C(7)H(6)BrClNO(2)S(−)·H(2)O, the K(+) cation is hepta­coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl­benzene­sulfonamidate anions, and one Br atom of one of the anions. The S—N distance of 1.584 (3) Å is consistent with...

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Detalles Bibliográficos
Autores principales: Spandana, H. S., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772410/
https://www.ncbi.nlm.nih.gov/pubmed/24046553
http://dx.doi.org/10.1107/S1600536813014979
Descripción
Sumario:In the title compound, K(+)·C(7)H(6)BrClNO(2)S(−)·H(2)O, the K(+) cation is hepta­coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl­benzene­sulfonamidate anions, and one Br atom of one of the anions. The S—N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O—H⋯Br and O—H⋯N hydrogen bonds.

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