cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide

In the title compound, [CoBr(CH(5)N)(C(3)H(10)N(2))(2)]Br(2), the cobalt(III) ion has a distorted octa­hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with an additional N atom and the Br atom occupying the axial positions. In the crystal, the complex catio...

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Autores principales: Kannan, P. S., Ganeshraja, A. S., Anbalagan, K., Govindan, E., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772414/
https://www.ncbi.nlm.nih.gov/pubmed/24046557
http://dx.doi.org/10.1107/S160053681301516X
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author Kannan, P. S.
Ganeshraja, A. S.
Anbalagan, K.
Govindan, E.
SubbiahPandi, A.
author_facet Kannan, P. S.
Ganeshraja, A. S.
Anbalagan, K.
Govindan, E.
SubbiahPandi, A.
author_sort Kannan, P. S.
collection PubMed
description In the title compound, [CoBr(CH(5)N)(C(3)H(10)N(2))(2)]Br(2), the cobalt(III) ion has a distorted octa­hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with an additional N atom and the Br atom occupying the axial positions. In the crystal, the complex cation and the two counter anions are linked via N—H⋯Br and C—H⋯Br hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-37724142013-09-17 cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide Kannan, P. S. Ganeshraja, A. S. Anbalagan, K. Govindan, E. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoBr(CH(5)N)(C(3)H(10)N(2))(2)]Br(2), the cobalt(III) ion has a distorted octa­hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with an additional N atom and the Br atom occupying the axial positions. In the crystal, the complex cation and the two counter anions are linked via N—H⋯Br and C—H⋯Br hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3772414/ /pubmed/24046557 http://dx.doi.org/10.1107/S160053681301516X Text en © Kannan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kannan, P. S.
Ganeshraja, A. S.
Anbalagan, K.
Govindan, E.
SubbiahPandi, A.
cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide
title cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide
title_full cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide
title_fullStr cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide
title_full_unstemmed cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide
title_short cis-Bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(III) dibromide
title_sort cis-bromido(methyl­amine)­bis­(propane-1,3-di­amine)­cobalt(iii) dibromide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772414/
https://www.ncbi.nlm.nih.gov/pubmed/24046557
http://dx.doi.org/10.1107/S160053681301516X
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AT anbalagank cisbromidomethylaminebispropane13diaminecobaltiiidibromide
AT govindane cisbromidomethylaminebispropane13diaminecobaltiiidibromide
AT subbiahpandia cisbromidomethylaminebispropane13diaminecobaltiiidibromide

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